Copper-Catalyzed Direct Sulfoximination of Azoles and Polyfluoroarenes under Ambient Conditions

被引：167

作者：

Miyasaka, Mitsuru ^{[2
]}

Hirano, Koji ^{[2
]}

Satoh, Tetsuya ^{[2
]}

Kowalczyk, Rafal ^{[1
]}

Bolm, Carsten ^{[1
]}

Miura, Masahiro ^{[2
]}

机构：

[1] Rhein Westfal TH Aachen, Inst Organ Chem, D-52056 Aachen, Germany

[2] Osaka Univ, Dept Appl Chem, Fac Engn, Suita, Osaka 5650871, Japan

来源：

ORGANIC LETTERS | 2011年 / 13卷 / 03期

关键词：

C-H BONDS; MEDIATED DIRECT ARYLATION; DIRECT ALKYNYLATION; DIRECT AMINATION; CARBON-HYDROGEN; TERMINAL ALKYNES; ARYL BROMIDES; AMIDATION; 1,3,4-OXADIAZOLES; HETEROCYCLES;

D O I：

10.1021/ol102844q

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The direct dehydrogenative C-N coupling of azoles or polyfluoroarenes with N-H sulfoximines proceeds effectively in the presence of a copper catalyst at room temperature under air to afford the corresponding N-arylsulfoximines in good to high yields.

引用

页码：359 / 361

页数：3

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