Synthesis of new tripodal Hantzsch 1,4-dihydropyridines under solvent-free condition and their conversion to the corresponding tripodal pyridines

被引:15
|
作者
Zolfigol, Mohammad Ali [2 ]
Kolvari, Eskandar [2 ]
Abdoli, Abbas [2 ]
Shiri, Morteza [1 ]
机构
[1] Alzahra Univ, Coll Sci, Dept Chem, Tehran 1993891176, Iran
[2] Bu Ali Sina Univ, Fac Chem, Hamadan 6517838683, Iran
关键词
1,4-Dihydropyridines; Tripodal 1,4-dihydropyridines; Tripodal pyridines; Solvent-free; NH4F; Oxone (R); ONE-POT SYNTHESIS; HETEROGENEOUS CONDITIONS; MILD CONDITIONS; AMBIENT-TEMPERATURE; OXIDATION; EFFICIENT; AROMATIZATION; DERIVATIVES; CATALYST; SYSTEM;
D O I
10.1007/s11030-009-9171-7
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
A mixture of beta-ketoester and tri-aldehydes in the presence of ammonium fluoride was converted to their corresponding tripodal 1,4-dihydropyridines under solvent-free condition with good yields. The obtained tripodal 1,4-dihydropyridines were also aromatized with oxone (R)/NaNO2/wet SiO2 system under mild and heterogeneous conditions quantitatively.
引用
收藏
页码:809 / 813
页数:5
相关论文
共 50 条
  • [21] Novel bipodal, tripodal, and tetrapodal 1,4-dihydropyridines - Microwave-assisted synthesis and structural confinements
    Rajesh, Kancherla
    Reddy, Bandapalli Palakshi
    Vijayakumar, Vijayaparthasarathi
    CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 2011, 89 (10): : 1236 - 1244
  • [22] Vitamin C-Catalyzed Hantzsch reaction under microwave condition: A greener access to 1,4-Dihydropyridines
    Ray, Devalina
    Yadav, Ram Naresh
    Banik, Bimal Krishna
    RESULTS IN CHEMISTRY, 2022, 4
  • [23] A clean procedure for the synthesis of 1,4-dihydropyridines via Hantzsch reaction in water
    Yang, Jinming
    Jiang, Chenning
    Yang, Jiaojiao
    Qian, Cunwei
    Fang, Dong
    GREEN CHEMISTRY LETTERS AND REVIEWS, 2013, 6 (03) : 262 - 267
  • [24] New Efficient Protocol for the Production of Hantzsch 1,4-Dihydropyridines Using RuCl3
    Suresh
    Kumar, Dhruva
    Sandhu, Jagir S.
    SYNTHETIC COMMUNICATIONS, 2009, 39 (11) : 1957 - 1965
  • [25] PPA-SiO2 Catalyzed One-Pot Synthesis of 1,4-Dihydropyridines Under Solvent-Free Conditions
    Khojastehnezhad, Amir
    Moeinpour, Farid
    Shams, Alireza
    SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2012, 42 (02) : 273 - 277
  • [26] Synthesis and biological evaluation of new series 1,4-dihydropyridines
    Ghorbani-Vaghei, Ramin
    Malaekehpoor, Seyedeh Mina
    Hasanein, Parisa
    Karamyan, Roya
    Asadbegy, Mostafa
    RESEARCH ON CHEMICAL INTERMEDIATES, 2016, 42 (05) : 4715 - 4731
  • [27] A Simple, Efficient, One-Pot Three-Component Domino Synthesis of Hantzsch Pyridines under Solvent-Free Condition
    Nasr-Esfahani, Masoud
    Karami, Bahador
    Behzadi, Masoume
    JOURNAL OF HETEROCYCLIC CHEMISTRY, 2009, 46 (05) : 931 - 935
  • [28] Synthesis of 1,4-Dihydropyridines Using Ce(SO4)2-SiO2 as Catalyst under Solvent-free Conditions
    Pei Wen
    Wang Qin
    Li Xiaonian
    Sun Li
    CHINESE JOURNAL OF CHEMISTRY, 2010, 28 (03) : 483 - 486
  • [29] One-pot synthesis of Dihydropyridines under solvent-free condition
    Cai, XH
    Zhang, GL
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2005, 25 (08) : 930 - 933
  • [30] Synthesis of 5-alkylated barbituric acids and 3-alkylated indoles via microwave-assisted three-component reactions in solvent-free conditions using Hantzsch 1,4-dihydropyridines as reducing agents
    Baruah, Biswajita
    Naidu, P. Seetham
    Borah, Pallabi
    Bhuyan, Pulak J.
    MOLECULAR DIVERSITY, 2012, 16 (02) : 291 - 298