Lignosulfonate biomass derived N and S co-doped porous carbon for efficient oxygen reduction reaction

被引:40
作者
Zhang, Mingli [1 ]
Song, Yanliang [2 ]
Tao, Hengcong [1 ]
Yan, Chao [3 ]
Masa, Justus [4 ,5 ]
Liu, Yongchao [3 ]
Shi, Xiaoyou [2 ]
Liu, Shizhen [1 ]
Zhang, Xu [2 ]
Sun, Zhenyu [1 ]
机构
[1] Beijing Univ Chem Technol, State Key Lab Organ Inorgan Composites, Beijing 100029, Peoples R China
[2] Beijing Univ Chem Technol, Coll Life Sci & Technol, Beying Key Lab Bioproc, Beijing 100029, Peoples R China
[3] Jiangsu Univ Sci & Technol, Sch Mat Sci & Engn, Zhenjiang 212003, Peoples R China
[4] Ruhr Univ Bochum, Analyt Chem Elektroanalyt & Sensor, D-44780 Bochum, Germany
[5] Kyambogo Univ, Dept Chem, POB 1, Kampala, Uganda
关键词
GRAPHENE OXIDE; SURFACE-AREA; NITROGEN; ELECTROCATALYSTS; LIGNIN; NANOSHEETS; CATALYSTS; NANOPARTICLES; GENERATION; CONVERSION;
D O I
10.1039/c8se00231b
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Finding sustainable, active, inexpensive, and stable electrocatalysts to replace Pt-based materials for the oxygen reduction reaction (ORR) remains a significant challenge. Here we report the use of functionalized lignin biomass as both carbon and dopant source for the direct synthesis of N and S dual-doped carbon sheet networks with abundant mesopores and high surface area. The resulting N and S-doped porous carbon exhibits good activity, long-term durability, and high selectivity for metal-free oxygen reduction electrocatalysis, approaching the performance of 20 wt% Pt/C, the state of the art ORR catalyst. Our method using natural biological resources thus offers a promising way to produce very promising noble metal-free ORR catalysts with potential application in alkaline fuel cells and metal-air batteries.
引用
收藏
页码:1820 / 1827
页数:8
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