Highly efficient and reusable supported Pd catalysts for Suzuki-Miyaura reactions of aryl chlorides

被引：74
|
作者：
Schweizer, Stephane [1 ]
Becht, Jean-Michel [1 ]
Le Drian, Claude [1 ]
机构：
[1] Univ Haute Alsace, Ecole Natl Super Chim Mulhouse, Lab Chim Organ & Bioorgan, CNRS,UMR 7015, F-68093 Mulhouse, France
来源：
ORGANIC LETTERS | 2007年 / 9卷 / 19期
关键词：
CROSS-COUPLING REACTIONS; ARYLBORONIC ACIDS; RECYCLABLE CATALYST; PALLADIUM CATALYSTS; ASSEMBLED COMPLEX; GENERAL-METHOD; C-C; LIGANDS; POLYMER; SILICA;
D O I：
10.1021/ol701460z
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Syntheses of air- and moisture-stable heterogeneous (tert-butylarylphosphino)polystyrene-supported Pd catalysts and their use for versatile Suzuki-Miyaura reactions of aryl chlorides and arylboronic acids under non-anhydrous conditions are reported. The catalysts are easily recovered by filtration. They can be used many times (more than seven) without showing any loss of activity, and the amount of Pd leached is extremely low (<0.1%).
引用
收藏
页码：3777 / 3780
页数：4
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