A general strategy for ligation of organic and biological molecules to Dawson and Keggin polyoxotungstates

被引：81
作者：
Micoine, Kevin
Hasenknopf, Bernold
Thorimbert, Serge
Lacote, Emmanuel
Malacria, Max
机构：
[1] Univ Paris 06, Inst Chim Mol FR 2769, Lab Chim Organ, CNRS,UMR 7611, F-75005 Paris, France
[2] Univ Paris 06, Inst Chim Mol FR 2769, Lab C1M2, CNRS,UMR 7071, F-75005 Paris, France
来源：
ORGANIC LETTERS | 2007年 / 9卷 / 20期
关键词：
D O I：
10.1021/ol701701f
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The copper-catalyzed azicle/alkyne cycloaddition (click chemistry) is used for the first time in polyoxometalate chemistry to graft any kind of organics (lipophilic, water-soluble, biologically relevant) to polyoxotungstates to generate hybrids. The method is not limited by solvent matching between the polyoxometallic platforms and the organic substrates.
引用
收藏
页码：3981 / 3984
页数：4
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