The impact of surfactants on the stability and thermal conductivity of graphene oxide de-ionized water nanofluids

被引:55
作者
Keklikcioglu Cakmak, Nese [1 ]
机构
[1] Sivas Cumhuriyet Univ, Dept Chem Engn, Fac Engn, TR-58140 Sivas, Turkey
关键词
Thermal conductivity; Graphene oxide; Surfactants; Nanofluid; Thermal properties; Stability; CARBON NANOTUBES; ENHANCEMENT; SUSPENSIONS; ADSORPTION; DISPERSION; VISCOSITY; SODIUM;
D O I
10.1007/s10973-019-09096-6
中图分类号
O414.1 [热力学];
学科分类号
摘要
The effects of three different surfactants were analyzed on the stability and thermal conductivity of GO/de-ionized water nanofluids. One surfactant was cationic, cetyltrimethyl ammonium bromide (CTAB), one was anionic, sodium dodecyl sulfate (SDS), and one was nonionic, TritonX-100 (TX-100). These were added to synthesized graphene oxide (GO) prepared in de-ionized water at different concentrations (0.01, 0.05, 0.1, 0.15, 0.2, and 0.25 mass%). The transient hot-wire technique was employed to measure the thermal conductivity of all nanofluids at 20-40 degrees C. The stability of the GO/de-ionized water nanofluids without a surfactant was better than that of nanofluids with a surfactant. The stability and dispersion of the nanofluid with SDS were considerably better than nanofluids with the other two surfactants. All nanofluids without a surfactant had higher thermal conductivity than de-ionized water at all temperatures. An increase in the GO concentration from 0.01 to 0.2 mass% improved thermal conductivity by 3.05 and 22.03% at 20 degrees C, respectively. A further increase to 0.25 mass% caused a 23.73% increase in thermal conductivity.
引用
收藏
页码:1895 / 1902
页数:8
相关论文
共 54 条
[21]   Experimental investigation of dispersion characteristics and thermal conductivity of various surfactants on carbon based nanomaterial [J].
Kim, Sedong ;
Tserengombo, Baasandulam ;
Choi, Soon-Ho ;
Noh, Jungpil ;
Huh, Sunchul ;
Choi, Byeongkeun ;
Chung, Hanshik ;
Kim, Junhyo ;
Jeong, Hyomin .
INTERNATIONAL COMMUNICATIONS IN HEAT AND MASS TRANSFER, 2018, 91 :95-102
[22]   Investigation of thermal conductivity, viscosity, and electrical conductivity of graphene based nanofluids [J].
Kole, Madhusree ;
Dey, T. K. .
JOURNAL OF APPLIED PHYSICS, 2013, 113 (08)
[23]   Important amino acid residues involved in folding and binding of protein-protein complexes [J].
Kulandaisamy, A. ;
Lathi, V. ;
ViswaPoorani, K. ;
Yugandhar, K. ;
Gromiha, M. Michael .
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2017, 94 :438-444
[24]   Study on flow boiling critical heat flux enhancement of graphene oxide/water nanofluid [J].
Lee, Seung Won ;
Kim, Kyung Mo ;
Bang, In Cheol .
INTERNATIONAL JOURNAL OF HEAT AND MASS TRANSFER, 2013, 65 :348-356
[25]   Graphene oxides cross-linked with hyperbranched polyethylenimines: Preparation, characterization and their potential as recyclable and highly efficient adsorption materials for lead(II) ions [J].
Liu, Yi ;
Xu, Li ;
Liu, Junshen ;
Liu, Xunyong ;
Chen, Caihua ;
Li, Guiying ;
Meng, Yanfeng .
CHEMICAL ENGINEERING JOURNAL, 2016, 285 :698-708
[26]   High Yield Preparation of Macroscopic Graphene Oxide Membranes [J].
Luo, Zhengtang ;
Lu, Ye ;
Somers, Luke A. ;
Johnson, A. T. Charlie .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (03) :898-+
[27]   Solubility study on the surfactants functionalized reduced graphene oxide [J].
Ma, Jing ;
Liu, Jianqiang ;
Zhu, Weihui ;
Qin, Wen .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2018, 538 :79-85
[28]   Improved Synthesis of Graphene Oxide [J].
Marcano, Daniela C. ;
Kosynkin, Dmitry V. ;
Berlin, Jacob M. ;
Sinitskii, Alexander ;
Sun, Zhengzong ;
Slesarev, Alexander ;
Alemany, Lawrence B. ;
Lu, Wei ;
Tour, James M. .
ACS NANO, 2010, 4 (08) :4806-4814
[29]   Bulk properties of aqueous graphene oxide and reduced graphene oxide with surfactants and polymers: adsorption and stability [J].
McCoy, Thomas M. ;
de Campo, Liliana ;
Sokolova, Anna V. ;
Grillo, Isabelle ;
Izgorodina, Ekaterina I. ;
Tabor, Rico F. .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2018, 20 (24) :16801-16816
[30]   Graphene oxide dispersions in organic solvents [J].
Paredes, J. I. ;
Villar-Rodil, S. ;
Martinez-Alonso, A. ;
Tascon, J. M. D. .
LANGMUIR, 2008, 24 (19) :10560-10564