Kinetics and mechanism of oxidation of some primary alcohols by N-bromobenzamide

被引：0
|
作者：
Siriah, VK [1 ]
Gupta, NM [1 ]
机构：
[1] Govt MGM Postgrad Coll, Dept Chem, Itarsi, India
来源：
ASIAN JOURNAL OF CHEMISTRY | 2000年 / 12卷 / 04期
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中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Kinetic studies in the oxidation of n-butyl alcohol and amyl alcohol with N-bromobenzamide has been made in aqueous acetic acid in presence of mercuric acetate. The reaction is first order, each with respect to oxidant and substrate. Order with respect to perchloric acid is fractional or first order depending upon the substrate concentration. Suggest protonation of the substrate in course of reaction. A mechanism consistent with the result has been proposed.
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页码：1071 / 1075
页数：5
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