Removal of cadmium(II) from aqueous solution by hydroxyapatite-encapsulated zinc ferrite (HAP/ZnFe2O4) nanocomposite: kinetics and isotherm study

被引:46
作者
Das, Krishna Chandra [1 ,2 ]
Dhar, Siddhartha S. [1 ]
机构
[1] Natl Inst Technol, Dept Chem, Silchar, Assam, India
[2] Gurucharan Coll, Dept Chem, Silchar, Assam, India
关键词
HAP; ZnFe(2)O(4)nanocomposite; Cd(II)ions; Pseudo-second-order; High adsorption capacity; HEAVY-METAL IONS; LEAD; ADSORPTION; NANOPARTICLES; CD(II); CD; MICROSPHERES; COMPOSITE; WATER; PB2+;
D O I
10.1007/s11356-020-09832-8
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
In this study, HAP/ZnFe(2)O(4)nanocomposite has been synthesized in two simple steps. The different characterization techniques confirm the fabrication of HAP/ZnFe(2)O(4)magnetic binary nanocomposite. The composite was successfully applied as nanoadsorbent for the elimination of Cd(II) ions from its aqueous solution. The composite was able to remove 89.6% of Cd(II) ions under optimum experimental conditions. The equilibrium sorption data were very much in agreement with the Freundlich adsorption model, and the maximum sorption capacity was recorded to be 120.33 mg/g. Kinetic data of the cadmium ion removal was well concurrent with the pseudo-second-order kinetics rate model. This magnetic HAP/ZnFe(2)O(4)nanocomposite can be applied as an environmentally friendly, low-cost, productive sorbent for the evacuation of Cd(II) ions from wastewater in light of its high sorption capacity.
引用
收藏
页码:37977 / 37988
页数:12
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