Chemical route to ferroelectric thin film capacitors

被引:4
|
作者
Mercurio, JP [1 ]
Yi, JH [1 ]
Thomas, P [1 ]
Manier, M [1 ]
机构
[1] Univ Limoges, Fac Sci, Lab Mat Ceram & Traitements Surface, ESA 6015, F-87060 Limoges, France
关键词
films; sol-gel processes; Aurivillius phases; ferroelectric properties;
D O I
10.1016/S0955-2219(98)00462-2
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
For the first time the fabrication of ferroelectric SrBi2(Ta,Nb)(2)O-9 thin film capacitors with RuO2 electrodes is conducted using a full chemical route. SrBi2(Ta,Nb)(2)O-9 sols were obtained from niobium and tantalum ethoxides mixed with bismuth and strontium 2-ethylhexanoates. RuO2 sols were prepared by dissolving an aqueous solution of ruthenium nitrosylnitrate into 2-methoxyethanol. Capacitors were fabricated by spin coating the precursor solutions on silicon wafers according to the Si/RuO2/ SrBi2(Ta,Nb)(2)O-9/RuO2 sequence. Fully crystallized crack-free materials (RuO2 and SrBi2(Ta,Nb)(2)O-9) were obtained bq, annealing at 700 degrees C for 2 h. Hysteresis loops (3-10 V) are similar to those observed using platinum electrodes. (C) 1999 Elsevier Science Limited. All rights reserved.
引用
收藏
页码:1439 / 1442
页数:4
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