Network of Palladium-Based Nanorings Synthesized by Liquid-Phase Reduction Using DMSO-H2O: In Situ Monitoring of Structure Formation and Drying Deformation by ASEM

被引:4
作者
Komenami, Takuki [1 ]
Yoshimura, Akihiro [1 ]
Matsuno, Yasunari [1 ]
Sato, Mari [2 ]
Sato, Chikara [2 ]
机构
[1] Chiba Univ, Grad Sch Sci & Engn, Chiba 2638522, Japan
[2] Natl Inst Adv Ind Sci & Technol, Hlth & Med Res Inst, Tsukuba, Ibaraki 3058566, Japan
关键词
atmospheric scanning electron microscopy; critical point drying; nanoparticles; nanostructures; precious metals; SCANNING-ELECTRON-MICROSCOPE; MICROMETER-SIZED PARTICLES; DIMETHYL-SULFOXIDE; SURFACE; NANOPARTICLES; STABILITY; COMPLEXES; CATALYSIS; SILICA;
D O I
10.3390/ijms21093271
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
We developed a liquid-phase synthesis method for Pd-based nanostructure, in which Pd dissolved in dimethyl sulfoxide (DMSO) solutions was precipitated using acid aqueous solution. In the development of the method, in situ monitoring using atmospheric scanning electron microscopy (ASEM) revealed that three-dimensional (3D) Pd-based nanonetworks were deformed to micrometer-size particles possibly by the surface tension of the solutions during the drying process. To avoid surface tension, critical point drying was employed to dry the Pd-based precipitates. By combining ASEM monitoring with critical point drying, the synthesis parameters were optimized, resulting in the formation of lacelike delicate nanonetworks using citric acid aqueous solutions. Precipitation using HCl acid aqueous solutions allowed formation of 500-nm diameter nanorings connected by nanowires. The 3D nanostructure formation was controllable and modifiable into various shapes using different concentrations of the Pd and Cl ions as the parameters.
引用
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页数:10
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