Two Iron Catalysts are Better than One: A General and Convenient Reduction of Aromatic and Aliphatic Primary Amides

被引：174
|
作者：
Das, Shoubhik [1 ]
Wendt, Bianca [1 ]
Moeller, Konstanze [1 ]
Junge, Kathrin [1 ]
Beller, Matthias [1 ]
机构：
[1] Univ Rostock, Leibniz Inst Katalyse eV, D-18059 Rostock, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 07期
关键词：
amides; amines; homogeneous catalysis; iron; reduction; ASYMMETRIC TRANSFER HYDROGENATION; CARBOXYLIC-ACID DERIVATIVES; PRIMARY AMINES; TERTIARY-AMINES; SECONDARY ALCOHOLS; CARBONYL-COMPOUNDS; HYDROSILYLATION; EFFICIENT; COMPLEXES; AMINATION;
D O I：
10.1002/anie.201108155
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
It takes two: For the reduction of amides to amines iron catalysts were developed. A combination of two different iron catalysts made possible the challenging reduction of primary amides (see picture). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：1662 / 1666
页数：5
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