Tandem Cycloaddition Reactions of Allenyl Diazo Compounds Forming Triquinanes via Trimethylenemethane Diyls

被引：29

作者：

Kang, Taek ^{[1
]}

Kim, Won-Yeob ^{[1
]}

Yoon, Yeokwon ^{[1
]}

Kim, Byung Gyu ^{[1
]}

Lee, Hee-Yoon ^{[1
]}

机构：

[1] Korea Adv Inst Sci & Technol, Dept Chem, Taejon 305701, South Korea

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2011年 / 133卷 / 45期

基金：

新加坡国家研究基金会;

关键词：

CAPTURE;

D O I：

10.1021/ja207591e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A tandem reaction strategy for forming triquinanes from linear allenyl diazo compounds through an intramolecular 1,3-dipolar cycloaddition reaction of an allenyl diazo group that generates a trimethylenemethane (TMM) diyl followed by an intramolecular [2 + 3] TMM diyl cycloaddition reaction has been developed. The new tandem cycloaddition reaction is readily applicable to the synthesis of complex molecules with high versatility and efficiency.

引用

页码：18050 / 18053

页数：4

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