Synthesis of homochiral zeolitic imidazolate frameworks via solvent-assisted linker exchange for enantioselective sensing and separation

被引：15
|
作者：
Zhuo, Chao [1 ]
Wang, Fei [1 ]
Zhang, Jian [1 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
来源：
CRYSTENGCOMM | 2018年 / 20卷 / 39期
关键词：
METAL-ORGANIC FRAMEWORKS; CAPTURE PROPERTIES; CRYSTAL-STRUCTURES; PORE OPENINGS; AMINO-ACID; DESIGN; RECOGNITION; TOPOLOGIES; ZMOFS; CAGES;
D O I：
10.1039/c8ce00403j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A pair of homochiral zeolitic imidazolate framework (S(R)-ZIF-78h) materials of GME topology possessing enantiopure benzimidazolate (S(R)-OH-bim) linkers have been synthesized via solvent-assisted linker exchange (SALE) of ZIF-78, which has been confirmed through H-1 NMR, elemental analysis, powder X-ray diffraction, gas adsorption and circular dichroism (CD). Remarkably, the representative S-ZIF-78h material exhibits permanent porosity and enantioselective sensing and separation ability towards proline.
引用
收藏
页码：5925 / 5928
页数：4
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