Design and characterization of novel conductive nanocomposites based on carbon nanotube modified liquid crystalline epoxy

被引:0
|
作者
Shen, Tengfei [1 ,2 ,3 ]
Gao, Lihua [1 ]
Wu, Fachao [1 ]
Lu, Mangeng [2 ]
机构
[1] North China Inst Sci & Technol, Dept Environm Engn, Yanjiao Beijing 101601, Peoples R China
[2] Chinese Acad Sci, Grad Univ, Guangzhou Inst Chem, Guangzhou 510650, Guangdong, Peoples R China
[3] Chinese Acad Sci, Grad Univ, Dept Chem & Chem Engn, Beijing 10049, Peoples R China
关键词
multiwalled carbon nanotube; liquid crystalline epoxy; morphology; thermal properties; conductive adhesive; CURING REACTION; COMPOSITES; THERMOSETS; BEHAVIOR; ADHESIVES; NETWORKS; RESINS;
D O I
10.1080/15685551.2015.1012620
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
In this work, a series of novel isotropically conductive adhesives (ICAs) based on multiwalled carbon nanotube (MWCNT)-modified liquid crystalline epoxy (LCE) resin was prepared. Different loadings of MWCNTs were used to produce LCE composites. Transmission electron microscope, scanning electron microscope, differential scanning calorimetry, polarized light optical microscopy, X-ray diffraction, electrical conductivity measurement, and tensile and flexural measurements were used to characterize the morphology, thermal, phase change, electrical, and mechanical properties of the prepared composites. The results showed that the added MWCNTs were dispersed well in the LCE matrix. The introducing MWCNTs did not show any major influence on typical curing peaks of LCE. Electrical conductivity at room temperature of the composites was increased significantly compared with neat LCE. The conductivity value of 10(-2)Scm(-1) was obtained at a weight concentration of only 0.5% MWCNT. In addition, tensile strength, Young's modulus, flexural strength, and flexural modulus of the composites were increased clearly compared with neat LCE matrix. These produced LCE composites with very low MWCNT loadings showed a great prospect of being used as ICAs.
引用
收藏
页码:323 / 332
页数:10
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