A comprehensive review of NOx and N2O mitigation from industrial streams

被引:54
作者
Alves, Luis [1 ]
Holz, Laura I., V [1 ,2 ,3 ]
Fernandes, Celina [1 ]
Ribeirinha, Paulo [1 ]
Mendes, Diogo [3 ]
Fagg, Duncan P. [2 ]
Mendes, Adelio [1 ]
机构
[1] Univ Porto, Fac Engn, LEPABE Lab Proc Engn Environm Biotechnol &, Rua Dr Roberto Frias, P-4200465 Porto, Portugal
[2] Univ Aveiro, Mech Engn Dept, Ctr Mech Technol & Automat, P-3810193 Aveiro, Portugal
[3] Bondalti Chem SA, Rua Amoniaco Portugues 10 Beduido, P-3860680 Estarreja, Portugal
关键词
NOx; N2O; Denitrification; Selective catalytic reduction; Catalytic decomposition; Selective non-catalytic reduction; Electron beam; Electrochemical reduction; SELECTIVE CATALYTIC-REDUCTION; ELECTRON-BEAM IRRADIATION; FLUE-GAS TREATMENT; OF-THE-ART; NITRIC-OXIDE; LOW-TEMPERATURE; ELECTROCHEMICAL REDUCTION; NITROGEN-OXIDES; REACTION-MECHANISM; DE-NOX;
D O I
10.1016/j.rser.2021.111916
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Mitigation of NOx and N2O emissions is a major concern as these substances can cause extensive damages to the atmosphere, soil, water, and humans. Selective catalytic reduction is currently the most effective and widespread technology to remove nitrogen oxides from flue streams. Other methods are also used on a case-by-case basis, most noticeably i) Catalytic decomposition of NOx and N2O, in which nitrogen oxides are decomposed in the absence of other reactants, and ii) selective non-catalytic reduction, which is generally applied when the use of catalytic beds is limited or impossible. Currently, all these technologies suffer limitations, a situation that has led to an interest in the conceptualization and development of new strategies. Electron beam irradiation and electrochemical reduction are some of the most promising prospective technologies, which have the potential to contribute to a rethinking of the state of the art in NOx and N2O mitigation. The current article provides an overview of all these technologies, considering process specifics and the advantages and disadvantages of their implementation.
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页数:16
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