Phosphine-Based Hyper-Cross-Linked Polymer-Supported Neutral Gold(I) Complex as a Recyclable Catalyst for the Regioselective Hydration of Alkynes to Ketones

被引：4

作者：

Shen, Lu ^{[1
]}

Han, Xingyou ^{[1
]}

Dong, Beixuan ^{[1
]}

Yang, Yong ^{[1
]}

Yang, Jiazhi ^{[1
]}

Li, Feng ^{[1
]}

机构：

[1] Nanjing Univ Sci & Technol, Sch Chem & Chem Engn, Nanjing 210094, Peoples R China

来源：

ACS APPLIED POLYMER MATERIALS | 2022年 / 4卷 / 10期

关键词：

hyper-cross-linked polymers; neutral gold(I) complex; hydration of alkynes; regioselective; recyclable catalyst; phosplwic ligand; FORMAL TOTAL-SYNTHESIS; TERMINAL ALKYNES; N-METHYLATION; ALCOHOLS; METHANOL; WATER; ACID; TRANSFORMATION; HYDROGENATION; ACTINORANONE;

D O I：

10.1021/acsapm.2c01167

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Functionalized hyper-cross-linked polymer-supported metal complexes have been developed as heterogeneous catalysts for organic synthesis and have attracted much attention. In this regard, a phosphine-based hyper-cross-linked polymersupported neutral gold(I) complex, Au@HCPs-PPh3, which is synthesized by incorporation of [(Me2S)AuCl] into a phosphinebased hyper-cross-linked polymer, is proven to be an efficient and general heterogeneous catalyst for the regioselective hydration of a series of alkynes to ketones. Furthermore, the synthesized catalyst is recycled six times without an obvious decrease in the catalytic activity.

引用

页码：7408 / 7416

页数：9

共 64 条

[41] Formal Total Synthesis of Actinoranone: Synthesis Approaches and Cytotoxic Studies
Novaes, Luiz F. T.
Goncalves, Kaliandra de Almeida
Trivella, Daniela B. B.
Pastre, Julio C.
[J]. JOURNAL OF ORGANIC CHEMISTRY, 2018, 83 (09) : 5160 - 5176
[42] Formal Total Synthesis of Actinoranone and Asymmetric Synthesis of Labda-7,13-(E)-dien-15-ol
Novaes, Luiz F. T.
Pastre, Julio C.
[J]. ORGANIC LETTERS, 2017, 19 (12) : 3163 - 3166
[43] Direct Heterogenization of the Ru-Macho Catalyst for the Chemoselective Hydrogenation of α,β-Unsaturated Carbonyl Compounds
Padmanaban, Sudakar
Gunasekar, Gunniya Hariyanandam
Yoon, Sungho
[J]. INORGANIC CHEMISTRY, 2021, 60 (10) : 6881 - 6888
[44] Hyper-Cross-Linked Polymers for the Capture of Aromatic Volatile Compounds
Paul, G.
Begni, F.
Melicchio, A.
Golemme, G.
Bisio, C.
Marchi, D.
Cossi, M.
Marchese, L.
Gatti, G.
[J]. ACS APPLIED POLYMER MATERIALS, 2020, 2 (02) : 647 - 658
[45] Benzene-Based Hyper-Cross-Linked Polymer with Enhanced Adsorption Capacity for CO2 Capture
Penchah, Hamid Ramezanipour
Ghaemi, Ahad
Gilani, Hossein Ghanadzadeh
[J]. ENERGY & FUELS, 2019, 33 (12) : 12578 - 12586
[46] The N-Alkylation of Sulfonamides with Alcohols in Water Catalyzed by the Water-Soluble Iridium Complex {Cp*Ir[6,6′-(OH)2bpy]( H2O)}[OTf]2
Qu, Panpan
Sun, Chunlou
Ma, Juan
Li, Feng
[J]. ADVANCED SYNTHESIS & CATALYSIS, 2014, 356 (2-3) : 447 - 459
[47] Solvent-free hydration of alkynes over a heterogeneous silver exchanged silicotungstic acid catalyst
Rao, K. T. Venkateswara
Prasad, P. S. Sai
Lingaiah, N.
[J]. GREEN CHEMISTRY, 2012, 14 (05) : 1507 - 1514
[48] Synthesis of Conjugated Mesoporous Hyper-cross-linked Polymers for Efficient Capture of Dibenzothiophene and Iodine
Shang, Zhikun
Zhao, Bing
Wu, Ziqi
Ding, Yun
Hu, Aiguo
[J]. ACS APPLIED MATERIALS & INTERFACES, 2020, 12 (50) : 56454 - 56461
[49] Highly Efficient and Selective N-Formylation of Amines with CO2 and H2 Catalyzed by Porous Organometallic Polymers
Shen, Yajing
Zheng, Qingshu
Chen, Zhe-Ning
Wen, Daheng
Clark, James H.
Xu, Xin
Tu, Tao
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2021, 60 (08) : 4125 - 4132
[50] Efficient Synthesis of Folate-Conjugated Hollow Polymeric Capsules for Accurate Drug Delivery to Cancer Cells
Song, Wenliang
Zhang, Yu
Yu, Deng-Guang
Tran, Chinh Hoang
Wang, Menglong
Varyambath, Anuraj
Kim, Jisu
Kim, Il
[J]. BIOMACROMOLECULES, 2021, 22 (02) : 732 - 742

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