Polymer building blocks: Self-assembly of silver(I) cyclotriphosphazene cationic columns

被引：59
|
作者：
Ainscough, EW [1 ]
Brodie, AM [1 ]
Depree, CV [1 ]
Jameson, GB [1 ]
Otter, CA [1 ]
机构：
[1] Massey Univ, Inst Fundamental Sci, Palmerston North, New Zealand
来源：
INORGANIC CHEMISTRY | 2005年 / 44卷 / 21期
关键词：
D O I：
10.1021/ic051334y
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The multimodal ligand hexakis(2-pyridyloxy)cyclotriphosphazene (L) and its 4-methyl-2-pyridyloxy analogue (MeL) react with Ag(I) to afford {[AgL](+)}(infinity) supramolecular cationic columns via self-assembly, with the anions occupying the intercolumnar channels. In contrast, the reaction of MeL with Cu(I) yields a dimetallic Cu(II) complex containing mu-OH and mu-4-methyl-2-pyridyloxylato bridges.
引用
收藏
页码：7325 / 7327
页数：3
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