Polymer building blocks: Self-assembly of silver(I) cyclotriphosphazene cationic columns

被引：59

作者：

Ainscough, EW ^{[1
]}

Brodie, AM ^{[1
]}

Depree, CV ^{[1
]}

Jameson, GB ^{[1
]}

Otter, CA ^{[1
]}

机构：

[1] Massey Univ, Inst Fundamental Sci, Palmerston North, New Zealand

来源：

INORGANIC CHEMISTRY | 2005年 / 44卷 / 21期

关键词：

D O I：

10.1021/ic051334y

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The multimodal ligand hexakis(2-pyridyloxy)cyclotriphosphazene (L) and its 4-methyl-2-pyridyloxy analogue (MeL) react with Ag(I) to afford {[AgL](+)}(infinity) supramolecular cationic columns via self-assembly, with the anions occupying the intercolumnar channels. In contrast, the reaction of MeL with Cu(I) yields a dimetallic Cu(II) complex containing mu-OH and mu-4-methyl-2-pyridyloxylato bridges.

引用

页码：7325 / 7327

页数：3

共 18 条

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