Synthesis and comparative study of three monomeric boronates by spectroscopic methods and X-ray crystallography

被引：45
|
作者：
Höpfl, H
Sánchez, M
Farfán, N
Barba, V
机构：
[1] Univ Autonoma Estado Morelos, Ctr Invest Quim, Cuernavaca 62210, Morelos, Mexico
[2] Inst Politecn Nacl, Ctr Invest & Estudios Avanzados, Dept Quim, Mexico City 07000, DF, Mexico
来源：
CANADIAN JOURNAL OF CHEMISTRY | 1998年 / 76卷 / 10期
关键词：
boronates; boron complexes; tridentate azomethine ligands; phenylboronic acid; X-ray crystallography;
D O I：
10.1139/cjc-76-10-1352
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Three boronates have been synthesized by reaction of tridentate azomethine ligands derived from salicylaldehyde with phenylboronic acid. The [5.4.0], [4.4.0], and [4.3.0]heterobicyclic structures obtained have been characterized by NMR spectroscopy and X-ray crystallography, whereby it could be proved that the [4.4.0]heterobicycle is the most stable one. Unexpectedly the salicylideneaminoethanol derivative does not lead to a macrocyclic structure, although molecular modeling reveals high ring strain for the monomeric product that is actually obtained.
引用
收藏
页码：1352 / 1360
页数：9
相关论文
共 50 条
  • [1] Phosphorus heterocycles: synthesis, spectroscopic study and X-ray crystallography of some new diazaphosphorinanes
    Khodayar Gholivand
    Zahra Shariatinia
    Hamid Reza Mahzouni
    Shadi Amiri
    Structural Chemistry, 2007, 18 : 653 - 660
  • [2] Phosphorus heterocycles: synthesis, spectroscopic study and X-ray crystallography of some new diazaphosphorinanes
    Gholivand, Khodayar
    Shariatinia, Zahra
    Mahzouni, Hamid Reza
    Amiri, Shadi
    STRUCTURAL CHEMISTRY, 2007, 18 (05) : 653 - 660
  • [3] Study of cyclic borinates obtained from piperidine- and piperazine alcohols by spectroscopic methods and X-ray crystallography
    Hopfl, H
    Farfan, N
    Castillo, D
    Santillan, R
    Gutierrez, A
    Daran, JC
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 553 (1-2) : 221 - 239
  • [4] Holographic methods for X-ray and electron crystallography
    Saldin, DK
    Shneerson, VL
    Vamvakas, JA
    Wild, DL
    MICRON, 1997, 28 (04) : 321 - 329
  • [5] X-Ray Crystallography
    Nespolo, Massimo
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2016, 72 : 168 - 170
  • [6] Synthesis, characterization and X-ray studies of new six-seven membered rings [4.5.0] heterobicyclic system of monomeric boronates
    Maria Rivera, Jose
    Mendez, Enrique
    Colorado-Peralta, Raul
    Rincon, Susana
    Farfan, Norberto
    Santillan, Rosa
    INORGANICA CHIMICA ACTA, 2012, 390 : 26 - 32
  • [7] Tetrahydropyrazolopyrazolones: Synthesis, X-ray crystallography and antimicrobial activity
    Bugarinovic, Jovana P.
    Stevanovic, Dragana
    Pesic, Marko S.
    Todosijevic, Anka
    Novakovic, Sladana
    Bogdanovic, Goran
    Mihailovic, Vladimir
    Stankovic, Jelena Katanic
    Damljanovic, Ivan
    JOURNAL OF MOLECULAR STRUCTURE, 2025, 1333
  • [8] N-2,4-dichlorobenzoyl phosphoric triamides: Synthesis, spectroscopic and X-ray crystallography studies
    Khodayar Gholivand
    Nasrin Oroujzadeh
    Zahra Shariatinia
    Journal of Chemical Sciences, 2010, 122 : 549 - 559
  • [9] N-2,4-Dichlorobenzoyl phosphoric triamides: Synthesis, spectroscopic and X-ray crystallography studies
    Gholivand, Khodayar
    Oroujzadeh, Nasrin
    Shariatinia, Zahra
    JOURNAL OF CHEMICAL SCIENCES, 2010, 122 (04) : 549 - 559
  • [10] Synthesis, characterization and X-ray studies of new chiral five-six-membered ring, [4.3.0] heterobicyclic system of monomeric boronates
    Maria Rivera, Jose
    Rincon, Susana
    Farfan, Norberto
    Santillan, Rosa
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2011, 696 (11-12) : 2420 - 2428
12345