Pd-Catalyzed Cyanation of (Hetero)Aryl Halides by Using Biphosphine Ligands

被引：23
|
作者：
Zhang, Shaoke [1 ]
Neumann, Helfried [1 ]
Beller, Matthias [1 ]
机构：
[1] Univ Rostock, Leibniz Inst Katalyse eV, Albert Einstein Str 29 A, D-18059 Rostock, Germany
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2018年 / 24卷 / 01期
关键词：
aryl halides; biphosphines; cyanation; palladium; synthetic methods; OLEFIN METATHESIS CATALYSTS; SECONDARY PHOSPHINE OXIDES; H BOND ACTIVATION; ARYL CHLORIDES; CONVENIENT PROCEDURE; EFFICIENT CATALYSTS; PHASE AMMOXIDATION; ARYLBORONIC ACIDS; PINCER COMPLEXES; CROSS-COUPLINGS;
D O I：
10.1002/chem.201704178
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Tetraadamantylbiphosphine (TABP; L1), which showed superior activity in the palladium-catalyzed cyanation of 4-chloroanisole compared to standard phosphines, was synthesized as a new ligand. The generality of the new catalytic system was shown by the cyanation reaction of approximately 30(hetero)aryl halides including hindered, electron-rich, and electron-poor aryl chlorides. These reactions constitute the first examples of using bi-phosphine ligands in Pd-catalyzed coupling reactions.
引用
收藏
页码：67 / 70
页数：4
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