Synthesis and crystal structure of a new three-dimensional supramolecule of copper(II) Schiff base complex

被引：0

作者：

Li Chun-Hong ^{[1
,2
,3
]}

Wang Qiang ^{[1
,2
,3
]}

Xu Yan-Qing ^{[1
,2
,3
]}

Hu Chang-Wen ^{[1
,2
,3
]}

机构：

[1] Beijing Inst Technol, Inst Chem Phys, Beijing 100081, Peoples R China

[2] Beijing Inst Technol, Dept Chem, Beijing 100081, Peoples R China

[3] Beijing Inst Technol, State Key Lab Explo Sci & Technol, Beijing 100081, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2008年 / 27卷 / 02期

关键词：

copper; crystal structure; Schiff base; hydrogen bonds;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new three-dimensional supramolecule composed of copper-Schiff base complex, [Cu(naphdien)]Cl center dot H2O, where naphdien is Schiff base of 2-hydroxy-1-naphthaldehyde and diethylenetriamine, has been synthesized and determined by single-crystal X-ray diffraction. It belongs to the monoclinic system, space group P2(1)/c, with a = 7.3490(15), b = 7.0847(16), c = 30.845(3) angstrom, beta = 95.33(3)degrees, V = 1599.0(5) angstrom(3), Z = 4, C15H20ClCuN3O2, M-r = 373.33, D-c = 1.551 g/cm(3), mu = 1.543 mm(-1), F(000) = 772, R = 0.0536 and wR = 0.0927 for 2788 unique reflections with 1659 observed ones (I > 2 sigma(I)). In the crystal structure, mononuclear units [Cu(naphdien)]Cl.H2O are linked into a two-dimensional framework via strong hydrogen bonds, and extended into a three-dimensional supramolecular structure through pi-pi stacking interactions.

引用

页码：187 / 190

页数：4

共 23 条

[1] Dicopper(I) and disilver(I) complexes of a thiophene-derived Schiff base macrocycle [J].

Adams, H ;

Fenton, DE ;

Ryan, SJ .

INORGANIC CHEMISTRY COMMUNICATIONS, 1999, 2 (02) :52-54

[2] LINEAR TRINUCLEAR COPPER(II) COMPLEXES DERIVED FROM ACYCLIC HEXADENTATE SCHIFF-BASE LIGANDS [J].

BAILEY, NA ;

FENTON, DE ;

HE, QY ;

TERRY, N ;

HAASE, W ;

WERNER, R .

INORGANICA CHIMICA ACTA, 1995, 235 (1-2) :273-279

[3] Synthesis of the ligand N,N′-bis(2-tert-butylthiobenzenylidene)-diethylenetriamine;: its reactivity with nickel(II) salts [J].

Bouwman, E ;

Henderson, RK ;

Reedijk, J ;

Veldman, N ;

Spek, AL .

INORGANICA CHIMICA ACTA, 1999, 287 (01) :105-108

[4] Dithiolate-containing macrocyclic complexes in which there is no thiolate bridging: synthesis, structure and electrochemistry of some dizinc(II) complexes [J].

Brooker, S ;

Davidson, TC .

INORGANICA CHIMICA ACTA, 2000, 306 (02) :227-231

[5] Structure and physico-chemical properties of hexadentate Schiff base zinc complexes derived from salicylaldehydes and triethylenetetramine [J].

Chantarasiri, N ;

Ruangpornvisuti, V ;

Muangsin, N ;

Detsen, H ;

Mananunsap, T ;

Batiya, C ;

Chaichit, N .

JOURNAL OF MOLECULAR STRUCTURE, 2004, 701 (1-3) :93-103

[6] In vivo anticancer, anti-inflammatory, and toxicity studies of mixed-ligand Cu(II) complexes of then and its Schiff dibases with heterocyclic aldehydes and 2-amino-2-thiazoline.: Crystal structure of [Cu(dien)(Br)(2a-2tzn)](Br)(H2O) [J].

Chaviara, AT ;

Christidis, PC ;

Papageorgiou, A ;

Chrysogelou, E ;

Hadjipavlou-Litina, DJ ;

Bolos, CA .

JOURNAL OF INORGANIC BIOCHEMISTRY, 2005, 99 (11) :2102-2109

[7] Copper(II) Schiff base coordination compounds of dien with heterocyclic aldehydes and 2-amino-5-methyl-thiazole:: synthesis, characterization, antiproliferative and antibacterial studies.: Crystal structure of CudienOOCl2 [J].

Chaviara, AT ;

Cox, PJ ;

Repana, KH ;

Papi, RM ;

Papazisis, KT ;

Zambouli, D ;

Kortsaris, AH ;

Kyriakidis, DA ;

Bolos, CA .

JOURNAL OF INORGANIC BIOCHEMISTRY, 2004, 98 (08) :1271-1283

[8] Aggregate manganese Schiff base moieties by terephthalate or acetate:: Dinuclear manganese and trinuclear mixed metal Mn2/Na complexes [J].

Chen, CN ;

Huang, DG ;

Zhang, XF ;

Chen, F ;

Zhu, HP ;

Liu, QT ;

Zhang, CX ;

Liao, DZ ;

Li, L ;

Sun, LC .

INORGANIC CHEMISTRY, 2003, 42 (11) :3540-3548

[9] Synthesis, crystal structure and magnetic behavior of two new binuclear complexes bridged by a pentadentate ligand:: [Ni2L2(NCS)2](ClO4)2 and [Ni2L2(NCO)2](ClO4)2 [L = pentadentate ligand] [J].

Deoghoria, S ;

Sain, S ;

Moulton, B ;

Zaworotko, MJ ;

Bera, SK ;

Chandra, SK .

POLYHEDRON, 2002, 21 (24) :2457-2461

[10] Structure and conformation of N-(2-methyl-5-chlorophenyl)salicylaldimine [J].

Elmali, A ;

Elerman, Y .

JOURNAL OF MOLECULAR STRUCTURE, 1998, 442 (1-3) :31-37

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