A 3D CuII Coordination Framework with μ4-/μ2-Oxalato Anions and a Bent Dipyridyl Coligand: Unique Zeolite-Type NiP2 Topological Network and Magnetic Properties

被引：33

作者：

Du, Miao ^{[1
,2
]}

Zhang, Zhi-Hui ^{[1
]}

Li, Cheng-Peng ^{[1
]}

Ribas-Artino, Jordi ^{[3
,4
]}

Aliaga-Alcalde, Nuria ^{[5
]}

Ribas, Joan ^{[5
]}

机构：

[1] Tianjin Normal Univ, Coll Chem, Tianjin Key Lab Struct & Performance Funct Mol, Tianjin 300387, Peoples R China

[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

[3] Univ Barcelona, Dept Quim Fis, E-08028 Barcelona, Spain

[4] Univ Barcelona, Fac Quim, IQTCUB, E-08028 Barcelona, Spain

[5] Univ Barcelona, Dept Quim Inorgan, E-08028 Barcelona, Spain

来源：

INORGANIC CHEMISTRY | 2011年 / 50卷 / 15期

基金：

中国国家自然科学基金;

关键词：

CRYSTAL; OXALATE; COMPLEXES;

D O I：

10.1021/ic200711e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of copper(II) nitrate, oxamide, and an angular bridging ligand 2,5-bis(4-pyridyl)-1,3,4-oxadiazole (4-bpo) under hydrothermal conditions affords a 3D pillared-layer coordination framework {[Cu-2(4-bpo)(ox)(2)](H2O)(4)}(n) (1) (ox = oxalate), featuring the unique zeolite-type NiP2 network and interesting properties.

引用

页码：6850 / 6852

页数：3

共 20 条

[1] The Cambridge Structural Database: a quarter of a million crystal structures and rising [J].

Allen, FH .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 2002, 58 (3 PART 1) :380-388

[2]

Cano J, 1998, CHEM-EUR J, V4, P476, DOI 10.1002/(SICI)1521-3765(19980310)4:3<476::AID-CHEM476>3.0.CO

[3]

2-8

[4] CRYSTAL, MOLECULAR, AND ELECTRONIC-STRUCTURE OF "CATENA-MU-OXALATO-AMMINE-COPPER(II) [J].

CAVALCA, L ;

TOMLINSON, AA ;

VILLA, AC ;

MANFREDO, AG ;

MANGIA, A .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1972, (03) :391-+

[5] Multifunctionality in hybrid magnetic materials based on bimetallic oxalate complexes [J].

Clemente-Leon, Miguel ;

Coronado, Eugenio ;

Marti-Gastaldo, Carlos ;

Romero, Francisco M. .

CHEMICAL SOCIETY REVIEWS, 2011, 40 (02) :473-497

[6] Angular Dipyridyl Ligands 2,5-Bis(4-pyridyl)-1,3,4-oxadiazole and Its 3-Pyridyl Analogue as Building Blocks for Coordination Architectures: Assemblies, Structural Diversity, and Properties [J].

Du, Miao ;

Bu, Xian-He .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2009, 82 (05) :539-554

[7]

Flanigen EM., 1991, Studies in Surface Science and Catalysis, V58, P13

[8] Enantioselective self-assembly of chiral bimetallic oxalate-based networks [J].

Gruselle, Michel ;

Train, Cyrille ;

Boubekeur, Karnal ;

Gredin, Patrick ;

Ovanesyan, Nicholas .

COORDINATION CHEMISTRY REVIEWS, 2006, 250 (19-20) :2491-2500

[9] Poly[methylamine-μ-oxalato-copper(II)] [J].

Keene, Tony D. ;

Hursthouse, Michael B. ;

Price, Daniel J. .

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 :M1373-M1375

[10] Lanthanide Contraction and Temperature-Dependent Structures of Lanthanide Coordination Polymers with Imidazole-4,5-Dicarboxylate and Oxalate [J].

Lu, Wen-Guan ;

Jiang, Long ;

Lu, Tong-Bu .

CRYSTAL GROWTH & DESIGN, 2010, 10 (10) :4310-4318

← 1 2 →