Novel (3,4)- and (4,5)-connected lanthanide metal-organic frameworks

被引：30
|
作者：
Wang, Xian-Wen [1 ]
Li, Xing [2 ]
Chen, Jing-Zhong [1 ]
Zheng, Guang [3 ]
Hong, Han-Lie [1 ]
机构：
[1] China Univ Geosci, Fac Chem Engn & Mat Sci, Wuhan 430074, Peoples R China
[2] Ningbo Univ, Fac Chem Engn & Mat Sci, Ningbo 315211, Peoples R China
[3] China Univ Geosci, Dept Math & Phys, Wuhan 430074, Peoples R China
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2008年 / 1卷 / 01期
关键词：
mixed nodes; lanthanides; metal-organic frameworks;
D O I：
10.1002/ejic.200700810
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The three-dimensional lanthanide noninterpenetrating metal-organic frameworks formulated as [Ln(3,5-pdc)-(C2O4)(0.5)(H2O)(2)]center dot H2O (Ln = Lu-III, Gd-III, Tm-III and Yb-III for complex 1-4, respectively; 3,5-pdc = 3,5-pyridinedicarboxylate) were synthesized by hydrothermal reactions of 3,5-H(2)pdc with lanthanide oxide and perchloric acid. Compound 1 shows (3,4)-connected (4.8(2))(4.8(5)) dmc-type topological network, and complexes 2-4 display the novel (4,5)-connected (4(4).6.8)(4(4).6(2).8(4)) xww-type topology. The lanthanide-mediated transformation of CO2 to oxalate under hydrothermal conditions was observed. The fluorescence properties of complexes 1-4 were investigated. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008).
引用
收藏
页码：98 / 105
页数：8
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