Synthesis and characterization of fullerophosphine-Au(I) complexes

被引：2
|
作者：
Chen, Chia-Hsiang [1 ]
Yeh, Wen-Yann [1 ]
机构：
[1] Natl Sun Yat Sen Univ, Dept Chem, Kaohsiung 804, Taiwan
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2015年 / 784卷
关键词：
Fullerene; Phosphine; Au(I) complex; Alkynyl complex; Structure elucidation; GOLD CATALYSIS; C-60; CHEMISTRY; PPH2(O-C6H4)(CH2NMECH)C-60; POLYMERIZATION; CYCLIZATION; ACTIVATION; ACETYLIDES; SPECTRA; ALKYNES;
D O I：
10.1016/j.jorganchem.2014.05.037
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Ligand substitution reaction of the fullerophosphine PPh2(o-C6H4)(CH2NMeCH)C-60 (1) with AuCl(SC4H8) affords AuCl(PPh2(o-C6H4)(CH2NMeCH)C-60) (2) in good yields. In the presence of AgPF6, compound 2 reacts with 1 to produce [Au(PPh2(o-C6H4)(CH2NMeCH)C-60)(2)]PF6 (3), where the Au(I) ion is coordinated by two molecules of 1 in a dumbbell-shaped feature. On the other hand, compound 1 undergoes a nucleophilic addition to (AuC equivalent to CPh)(n) to generate Au(C equivalent to CPh)(PPh2(o-C6H4)(CH2NMeCH)C-60) (4). The structures of 2e4 have been determined by an X-ray diffraction study. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码：41 / 45
页数：5
相关论文
共 50 条
  • [21] Synthesis of Au(I) Trifluoromethyl Complexes. Oxidation to Au(III) and Reductive Elimination of Halotrifluoromethanes
    Blaya, Maria
    Bautista, Delia
    Gil-Rubio, Juan
    Vicente, Jose
    ORGANOMETALLICS, 2014, 33 (22) : 6358 - 6368
  • [22] Homobimetallic Au(I)-Au(I) and Heterotrimetallic Au(I)-Fe(II)-Au(I) Complexes with Dialkyldithiophosphates and Phosphine Ligands: Structural Characterization, DFT Analysis, and Tyrosinase Inhibitory and Biological Effects
    Neshat, Abdollah
    Mahdavi, Atiyeh
    Yousefshahi, Mohammad Reza
    Cheraghi, Mahdi
    Mobarakeh, Ali Mousavizadeh
    Mohammadi, Saiedeh
    Eigner, Vaclav
    Kucerakova, Monika
    Dusek, Michal
    Kaboudin, Babak
    ACS OMEGA, 2023, 8 (23): : 20423 - 20439
  • [23] Synthesis, structure, and solution behavior of cationic Au(I) enamine complexes
    Sriram, Madhavi
    Jones, Amanda C.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2013, 245
  • [24] Neutral Binuclear Ag(I) and Au(I) N-Heterocyclic Carbene Complexes of Axially Chiral and Racemic Scaffolds: Synthesis and Characterization
    Mahule, Sonali Ramgopal
    Gangwar, Manoj Kumar
    Vishnoi, Pratap
    CHEMISTRYSELECT, 2018, 3 (14): : 4023 - 4026
  • [25] Synthesis and characterization of homoleptic copper (I) thiolate complexes
    Pratt, Jade
    Power, Philip
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 254
  • [26] Synthesis and characterization of alkynes β-diketonate copper(I) complexes
    Delgado, S
    Corripio, D
    Moreno, C
    INORGANICA CHIMICA ACTA, 2004, 357 (11) : 3205 - 3210
  • [27] Synthesis, structure and characterization of binuclear copper(I) complexes
    Ruina Yang
    Kunhua Lin
    Yimin Hou
    Dongmei Wang
    Douman Jin
    Baosheng Luo
    Liaorong Chen
    Transition Metal Chemistry, 1997, 22 : 254 - 258
  • [28] SYNTHESIS AND CHARACTERIZATION OF SOME COPPER(I) PHENANTHROLINE COMPLEXES
    PALLENBERG, AJ
    KOENIG, KS
    BARNHART, DM
    INORGANIC CHEMISTRY, 1995, 34 (11) : 2833 - 2840
  • [29] SYNTHESIS AND CHARACTERIZATION OF COPPER(I) HALIDE IMINE COMPLEXES
    RAUBENHEIMER, HG
    CRONJE, S
    KRUGER, GJ
    OLIVIER, PJ
    POLYHEDRON, 1995, 14 (17-18) : 2389 - 2396
  • [30] Synthesis and spectroscopic characterization of copper(I)-diazene complexes
    Ishikawa, Y
    Ono, T
    Miyashita, Y
    Okamoto, K
    Fujisawa, K
    Lehnert, N
    JOURNAL OF INORGANIC BIOCHEMISTRY, 2003, 96 (01) : 157 - 157
12345