Effect of bio-functional MAO layers on the electrochemical behaviour of highly porous Ti

被引:28
作者
Alves, A. C. [1 ]
Costa, A., I [1 ]
Toptan, F. [1 ,2 ,3 ]
Alves, J. L. [1 ,2 ]
Leonor, I [4 ,5 ]
Ribeiro, E. [4 ,5 ]
Reis, R. L. [4 ,5 ]
Pinto, A. M. P. [1 ,2 ]
Fernandes, J. C. S. [6 ,7 ]
机构
[1] Univ Minho, CMEMS UMinho Ctr MicroElectroMech Syst, Guimaraes, Portugal
[2] Univ Minho, Dep Mech Engn, Guimaraes, Portugal
[3] UNESP, IBTN Br Brazilian Branch Inst Biomat Tribocorros, Av Eng Luiz Edmundo Carrijo Coube 14-01, BR-17033360 Bauru, SP, Brazil
[4] Univ Minho, 3Bs Res Grp Biomat Biodegradables & Biomimet, Guimaraes, Portugal
[5] Univ Minho, ICVS 3Bs PT Govt Assoc Lab, Braga, Guimaraes, Portugal
[6] Univ Lisbon, Dept Chem Engn, Inst Super Tecn, Lisbon, Portugal
[7] CQE Inst Super Tecn, Lisbon, Portugal
关键词
Powder metallurgy; Porous Ti; Micro-arc oxidation; Corrosion; EIS; TITANIUM-OXIDE FILMS; MECHANICAL-PROPERTIES; CORROSION BEHAVIOR; PORE STRUCTURE; SPACE-HOLDER; SURFACE CHARACTERISTICS; ALLOY; CA; HYDROXYAPATITE; GROWTH;
D O I
10.1016/j.surfcoat.2020.125487
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Ti foams are attractive for orthopaedic applications due to reduced Young's modulus and ability of bone ingrowth. However, poor corrosion behaviour and lack of bioactivity are yet to be overcome. In the present work, highly porous Ti samples were processed by powder metallurgy with space holder technique and bio-functionalized by micro-arc oxidation, resulting in nano/micro structured TiO2 surfaces containing bioactive elements. The electrochemical behaviour of these bio-functionalized highly porous Ti surfaces was evaluated through potentiodynamic polarization and EIS in physiological solution at body temperature. Results showed that bio-functionalization improved the corrosion behaviour of highly porous Ti. However, increased macro-porosity led to an increased corrosion rate.
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页数:11
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