Syntheses of mixed-ligand ruthenium(II) complexes with a terpyridine or a tris(pyrazolyl)methane and a bidentate ligand: their application for catalytic hydroxylation of alkanes

被引：23

作者：

Yamaguchi, M ^{[1
]}

Iida, T ^{[1
]}

Yamagishi, T ^{[1
]}

机构：

[1] Tokyo Metropolitan Univ, Grad Sch Engn, Dept Appl Chem, Tokyo 1920397, Japan

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 1998年 / 1卷 / 08期

关键词：

oxidation catalyst; alkane hydroxylation; ruthenium complexes; mixed-ligand complexes;

D O I：

10.1016/S1387-7003(98)00080-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new mixed-ligand chlororuthenium(II) complexes [RuCl(L) (tpy)]Cl-n and [RuCl(L) (tpm)] Cl-n(L = bpy, dmpa or dmgly; n = 0 or 1) were prepared, and the catalytic activity for alkane oxidation using m-chloroperbenzoic acid was examined. Alcohol was the main product: oxidation of adamantane, cyclooctane or ethylbenzene gave hydroxylated products, 1-adamantanol (66%), cyclooctanol (22%) or 1-phenylethanol (48%), respectively. (C) 1998 Elsevier Science S.A. All rights reserved.

引用

页码：299 / 301

页数：3