Cyclization of polyenes. Part 57. An efficient construction of trinervitane and kempane skeletons from the common intermediate

被引：14

作者：

Kato, T ^{[1
]}

Tanaka, M ^{[1
]}

Hoshikawa, M ^{[1
]}

Yagi, M ^{[1
]}

机构：

[1] Sci Univ Tokyo, Fac Sci, Dept Chem, Shinjuku Ku, Tokyo 1628601, Japan

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 41期

关键词：

D O I：

10.1016/S0040-4039(98)01643-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Tricyclic trinervitane and tetracyclic kempane skeletons are constructed from the common intermediate possessing bicyclic serotrinervitane skeleton on the basis of biogenetical consideration. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：7553 / 7556

页数：4

共 15 条

[1]

BAER R, 1984, TETRAHEDRON LETT, V25, P579

[2] SECOTRINERVITANE, A NOVEL BICYCLIC DITERPENE SKELETON FROM A TERMITE SOLDIER [J].

BRAEKMAN, JC ;

DALOZE, D ;

DUPONT, A ;

PASTEELS, J ;

TURSCH, B ;

DECLERCQ, JP ;

GERMAIN, G ;

VANMEERSSCHE, M .

TETRAHEDRON LETTERS, 1980, 21 (28) :2761-2762

[3] TOTAL SYNTHESIS OF (+/-)-KEMPENE-2 [J].

DAUBEN, WG ;

FARKAS, I ;

BRIDON, DP ;

CHUANG, CP ;

HENEGAR, KE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (15) :5883-5884

[4] EXTREME INTRASPECIFIC CHEMICAL VARIABILITY IN SOLDIER DEFENSE SECRETIONS OF ALLOPATRIC AND SYMPATRIC COLONIES OF LONGIPEDITERMES-LONGIPES [J].

GOH, SH ;

CHUAH, CH ;

THO, YP ;

PRESTWICH, GD .

JOURNAL OF CHEMICAL ECOLOGY, 1984, 10 (06) :929-944

[5] SYNTHESIS OF SECOTRINERVITANES, UNIQUE BICYCLIC DITERPENES FROM TERMITES [J].

HIRUKAWA, T ;

SHUDO, T ;

KATO, T .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1993, (02) :217-225

[6] CYCLIZATION OF POLYENES .49. CYCLIZATION OF EPOXYNEOCEMBRENE DERIVATIVES TO SECOTRINERVITANES [J].

HIRUKAWA, T ;

KOARAI, A ;

KATO, T .

JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (14) :4520-4525

[7] FIRST SYNTHESIS OF THE TRINERVITANE SYSTEM FROM SECOTRINERVITANE BY TRANSANNULAR RING CONSTRUCTION [J].

HIRUKAWA, T ;

SUZUKI, T ;

TANAKA, M ;

KATO, T .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (03) :311-312

[8]

KASIBUCHI Y, 1998, IN PRESS HETEROCYCLE

[9] A BIOGENETIC SYNTHESIS OF (+/-)-SECOTRINERVITEN-2-BETA,3-ALPHA-DIOL [J].

KATO, T ;

HIRUKAWA, T ;

YAMAMOTO, Y .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (13) :977-978

[10]

NODA E, 1996, TEAC S PAPER, P119

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