A polymer supported ascorbate functionalized task specific ionic liquid: an efficient reusable catalyst for 1,3-dipolar cycloaddition

被引:17
|
作者
Patil, Jayavant D. [1 ]
Patil, Supriya A. [2 ]
Pore, Dattaprasad M. [1 ]
机构
[1] Shivaji Univ, Dept Chem, Kolhapur 416004, Maharashtra, India
[2] Hanyang Univ, Dept Chem, Seoul 133791, South Korea
关键词
ONE-POT SYNTHESIS; CLICK CHEMISTRY SYNTHESIS; ARYL BORONIC ACIDS; 1,4-DISUBSTITUTED 1,2,3-TRIAZOLES; COPPER NANOPARTICLES; TERMINAL ALKYNES; SODIUM-AZIDE; MULTICOMPONENT SYNTHESIS; HUISGEN CYCLOADDITION; ORGANIC AZIDES;
D O I
10.1039/c4ra16481d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel polymer supported ascorbate functionalized task specific ionic liquid was designed and synthesized. It has been demonstrated that the synthesized polymer supported ionic liquid acts as an efficient catalyst for regioselective Huisgen 1,3-dipolar cycloaddition of aryldiazoniumtetrafluoroborate, sodiumazide and terminal alkyne, which provide a series of 1,4-disubstituted-1,2,3-triazoles in high yields at room temperature as well as showing an aptitude for in situ incorporation of copper.
引用
收藏
页码:21396 / 21404
页数:9
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