Conductive Polymer Intercalation Tunes Charge Transfer and Sorption-Desorption Properties of LDH Enabling Efficient Alkaline Water Oxidation

被引:40
作者
Ju, Min [1 ]
Cai, Rongming [1 ]
Ren, Jiazheng [1 ]
Chen, Jinxi [1 ]
Qi, Limin [2 ]
Long, Xia [1 ]
Yang, Shihe [1 ]
机构
[1] Peking Univ, Sch Chem Biol & Biotechnol, Shenzhen Grad Sch, Guangdong Prov Key Lab Nanomicro Mat Res, Shenzhen 518055, Peoples R China
[2] Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci BNLMS, Beijing 100871, Peoples R China
关键词
LDH-CP hybrid catalyst; interlayer confined polymerization; electrocatalysis for OER; in situ EQCM-D; in situ SECM; LAYERED DOUBLE HYDROXIDES; ENERGY-STORAGE; NANOSHEETS; ELECTROCATALYSTS; CATALYSTS; RECONSTRUCTION; CONVERSION; GRAPHENE;
D O I
10.1021/acsami.1c08429
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Controlling and tuning surface properties of a catalyst have always been a prime challenge for efficient hydrogen production via water splitting. Here, we report a facile method for tuning both charger transfer and sorption-desorption properties of NiFe layered double hydroxide (LDH) by intercalating a conductive polymer of polypyrrole (ppy) via an interlayer confined polymerization synthesis (ICPS) process. Ex situ characterizations and in situ electrochemical quartz-crystal microbalance with dissipation (EQCM-D) tracking experiments showed that the intercalated ppy not only improved the charge transfer property of the resulting hybrid catalyst LDH-ppy but also made it more flexible and adaptive for quick and reversible sorption-desorption of reactants and intermediates during the oxygen evolution reaction (OER) process. Consequently, the as-prepared LDH-ppy exhibited a doubled catalytic current density over the bare LDH, as visualized by in situ scanning electrochemical microscopy (SECM) at the subnanometer scale. This work sheds light on orchestrating the charge and sorbate transfer abilities of catalysts for efficient water splitting by smartly combining inorganic and organic layers.
引用
收藏
页码:37063 / 37070
页数:8
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