Ex situ Sn diffusion: a well-suited technique for enhancing the photovoltaic properties of a SnS absorber layer

被引:18
作者
Sajeesh, T. H. [1 ]
Kartha, C. Sudha [1 ]
Sanjeeviraja, C. [2 ]
Abe, T. [3 ]
Kashiwaba, Y. [3 ]
Vijayakumar, K. P. [1 ]
机构
[1] Cochin Univ Sci & Technol, Dept Phys, Cochin 682022, Kerala, India
[2] Alagappa Univ, Sch Phys, Karaikkudi 630003, Tamil Nadu, India
[3] Iwate Univ, Dept Elect & Elect Engn, Morioka, Iwate 0208551, Japan
关键词
THIN-FILMS; ENERGY; PHOTOCONDUCTIVITY; OPTIMIZATION;
D O I
10.1088/0022-3727/43/44/445102
中图分类号
O59 [应用物理学];
学科分类号
摘要
Sn atoms were thermally diffused into tin (II) sulfide (SnS) films prepared using chemical spray pyrolysis. This was achieved by depositing a layer of Sn metal over SnS films followed by annealing of the Sn/SnS bilayer films at 100 degrees C in high vacuum for 30 min. There was no contamination due to the formation of additional phases of Sn compounds up to a very high percentage of Sn diffusion. Contamination due to Sn-O-S phase was removed by Sn diffusion. The samples were optimized to achieve higher photosensitivity and low resistivity. All these enhanced properties were obtained without altering the optimum band gap of the SnS film which is suitable for maximum photovoltaic conversion efficiency.
引用
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页数:6
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共 28 条
  • [1] Detection of singly ionized state of two-electron tin centers with negative correlation energy in Pb1-xSnxS alloys
    Castro, R. A.
    Nemov, S. A.
    Seregin, P. P.
    [J]. SEMICONDUCTORS, 2006, 40 (08) : 898 - 900
  • [2] IR PHOTOCONDUCTIVITY IN P-SNS/P-SNS
    CHAMBERLAIN, JM
    MERDAN, M
    [J]. JOURNAL OF PHYSICS C-SOLID STATE PHYSICS, 1977, 10 (19): : L571 - L574
  • [3] Low resistive micrometer-thick SnS:Ag films for optoelectronic applications
    Devika, M.
    Reddy, N. Koteeswara
    Ramesh, K.
    Gunasekhar, K. R.
    Gopal, E. S. R.
    Reddy, K. T. Ramakrishna
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2006, 153 (08) : G727 - G733
  • [4] Microstructure dependent physical properties of evaporated tin sulfide films
    Devika, M.
    Reddy, K. T. Ramakrishna
    Reddy, N. Koteeswara
    Ramesh, K.
    Ganesan, R.
    Gopal, E. S. R.
    Gunasekhar, K. R.
    [J]. JOURNAL OF APPLIED PHYSICS, 2006, 100 (02)
  • [5] Goswami A., 1996, THIN FILM FUNDAMENTA
  • [6] Thin-film solar cells: review of materials, technologies and commercial status
    Green, Martin A.
    [J]. JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2007, 18 (Suppl 1) : S15 - S19
  • [7] GUO Y, 2009, P ISES SOL WORLD C 2, V1, P1337
  • [8] Characterization of spray pyrolysed indium sulfide thin films
    John, TT
    Bini, S
    Kashiwaba, Y
    Abe, T
    Yasuhiro, Y
    Kartha, CS
    Vijayakumar, KP
    [J]. SEMICONDUCTOR SCIENCE AND TECHNOLOGY, 2003, 18 (06) : 491 - 500
  • [9] Optimization of photoconductivity in vacuum-evaporated tin sulfide thin films
    Johnson, JB
    Jones, H
    Latham, BS
    Parker, JD
    Engelken, RD
    Barber, C
    [J]. SEMICONDUCTOR SCIENCE AND TECHNOLOGY, 1999, 14 (06) : 501 - 507