Solubility of naphthalene in liquid and supercritical ammonia

被引:0
作者
Kim, JR [1 ]
Lentz, H [1 ]
Park, TK [1 ]
机构
[1] UNIV GESAMTHSCH SIEGEN,FACHBEREICH 8,D-57068 SIEGEN,GERMANY
来源
ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS | 1996年 / 193卷
关键词
solubility; entropy; supercritical ammonia; thermodynamics;
D O I
10.1524/zpch.1996.193.Part_1_2.087
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The solubilities of naphthalene in liquid and supercritical ammonia have been measured for temperature from 333.15 to 497.15 K and pressures between 5 and 120 MPa. For pressures higher than 10 MPa and temperatures higher than 333.15 K the results can be described by a simple equation which enables interpolation and extrapolation especially with respect to pressure or density. Logarithmic isobars are not straight lines and the transition entropies calculated for temperatures higher than 373.15 K are negative at low pressures and positive for pressures higher than 22.0 MPa.
引用
收藏
页码:87 / 94
页数:8
相关论文
共 50 条
  • [41] Solubility of red palm oil in supercritical carbon dioxide: Measurement and modelling
    Lee, Wan Jun
    Tan, Chin Ping
    Sulaiman, Rabiha
    Chong, Gun Hean
    CHINESE JOURNAL OF CHEMICAL ENGINEERING, 2018, 26 (05) : 964 - 969
  • [42] First catalytic hydroaminomethylation in supercritical ammonia
    Klein, Holger
    Jackstell, Ralf
    Kant, Michael
    Martin, Andreas
    Beller, Matthias
    CHEMICAL ENGINEERING & TECHNOLOGY, 2007, 30 (06) : 721 - 725
  • [43] Stability of materials in supercritical ammonia solutions
    Pimputkar, Siddha
    Malkowski, Thomas F.
    Griffiths, Steven
    Espenlaub, Andrew
    Suihkonen, Sarni
    Speck, James S.
    Nakamura, Shuji
    JOURNAL OF SUPERCRITICAL FLUIDS, 2016, 110 : 193 - 229
  • [44] Solubility measurements of noble metal acetylacetonates in supercritical carbon dioxide by high performance liquid chromatography (HPLC)
    Yoda, Satoshi
    Mizuno, Yoko
    Furuya, Takeshi
    Takebayashi, Yoshihiro
    Otake, Katsuto
    Tsuji, Tomoya
    Hiaki, Toshihiko
    JOURNAL OF SUPERCRITICAL FLUIDS, 2008, 44 (02) : 139 - 147
  • [45] Effects of supercritical ammonia on bamboo pulping
    ZHANG Yuan-jing
    Forest Ecosystems, 2011, (01) : 80 - 84
  • [46] Decomposition of supercritical ammonia and modeling of supercritical ammonia-nitrogen-hydrogen solutions with applicability toward ammonothermal conditions
    Pimputkar, Siddha
    Nakamura, Shuji
    JOURNAL OF SUPERCRITICAL FLUIDS, 2016, 107 : 17 - 30
  • [47] Modeling of the solubility of a solid in a liquid for organic systems
    Esina, Z. N.
    Korchuganova, M. R.
    THEORETICAL FOUNDATIONS OF CHEMICAL ENGINEERING, 2015, 49 (03) : 313 - 321
  • [48] Molecular thermodynamics for solubility of gas in binary liquid
    Yang F.
    Wang X.
    Chen Q.
    Tan H.
    Huagong Xuebao/CIESC Journal, 2019, 70 : 62 - 69
  • [49] Solubility of radioactive inorganic salt in supercritical water
    Qiang Qin
    Shuai Wang
    Honghua Peng
    Yanbo Qiao
    Hong Zhang
    Kai Wang
    Xueyang Liu
    Zhenghua Qian
    Liubin He
    Jun Cai
    Yulan Li
    Xiaobin Xia
    Journal of Radioanalytical and Nuclear Chemistry, 2018, 317 : 947 - 957
  • [50] Solubility of ammonium palmitate in supercritical carbon dioxide
    A. A. Zakharov
    T. R. Bilalov
    F. M. Gumerov
    Russian Journal of Physical Chemistry B, 2016, 10 : 1092 - 1098