Solubility of naphthalene in liquid and supercritical ammonia

被引:0
|
作者
Kim, JR [1 ]
Lentz, H [1 ]
Park, TK [1 ]
机构
[1] UNIV GESAMTHSCH SIEGEN,FACHBEREICH 8,D-57068 SIEGEN,GERMANY
关键词
solubility; entropy; supercritical ammonia; thermodynamics;
D O I
10.1524/zpch.1996.193.Part_1_2.087
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The solubilities of naphthalene in liquid and supercritical ammonia have been measured for temperature from 333.15 to 497.15 K and pressures between 5 and 120 MPa. For pressures higher than 10 MPa and temperatures higher than 333.15 K the results can be described by a simple equation which enables interpolation and extrapolation especially with respect to pressure or density. Logarithmic isobars are not straight lines and the transition entropies calculated for temperatures higher than 373.15 K are negative at low pressures and positive for pressures higher than 22.0 MPa.
引用
收藏
页码:87 / 94
页数:8
相关论文
共 50 条
  • [21] Effect of halogen species of acidic mineralizer on solubility of GaN in supercritical ammonia
    Tomida, Daisuke
    Kuribayashi, Taketo
    Suzuki, Kousuke
    Kagamitani, Yuji
    Ishiguro, Toru
    Fukuda, Tsuguo
    Yokoyama, Chiaki
    JOURNAL OF CRYSTAL GROWTH, 2011, 325 (01) : 52 - 54
  • [22] Solubility of trifluoroethoxyphthalocyanines and -subphthalocyanines in liquid and supercritical carbon dioxide
    Das, Banibrata
    Tokunaga, Etsuko
    Shibata, Norio
    Kobayashi, Nagao
    JOURNAL OF FLUORINE CHEMISTRY, 2010, 131 (05) : 652 - 654
  • [23] The solubility of non-radiated cholesterol in liquid ammonia
    Gustavson, RG
    Goodman, JB
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1927, 49 : 2526 - 2528
  • [24] The solubility of metallic lithium in liquid ammonia at low temperatures
    Johnson, WC
    Piskur, MM
    JOURNAL OF PHYSICAL CHEMISTRY, 1933, 37 (01): : 93 - 99
  • [25] SOLUBILITY OF CELLULOSE IN LIQUID AMMONIA-SALT SOLUTIONS
    HUDSON, SM
    CUCULO, JA
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1980, 179 (MAR): : 24 - CELL
  • [26] THE SOLUBILITY OF CELLULOSE IN LIQUID AMMONIA-SALT SOLUTIONS
    HUDSON, SM
    CUCULO, JA
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1980, 18 (12) : 3469 - 3481
  • [27] Solubility of ammonia in liquid mixtures of (water plus methanol)
    Schaefer, Dirk
    Vogt, Mathias
    Kamps, Alvaro Perez-Salado
    Maurer, Gerd
    FLUID PHASE EQUILIBRIA, 2007, 261 (1-2) : 306 - 312
  • [28] SOLUBILITY OF AMMONIA IN LIQUID WATER AND GENERATION OF TRACE LEVELS OF STANDARD GASEOUS AMMONIA
    DASGUPTA, PK
    DONG, S
    ATMOSPHERIC ENVIRONMENT, 1986, 20 (03) : 565 - 570
  • [29] Polarizable Interaction Model for Liquid, Supercritical, and Aqueous Ammonia
    Orabi, Esam A.
    Lamoureux, Guillaume
    JOURNAL OF CHEMICAL THEORY AND COMPUTATION, 2013, 9 (04) : 2035 - 2051
  • [30] Solubility and dissolution kinetics of GaN in supercritical ammonia in presence of ammonoacidic and ammonobasic mineralizers
    Schimmel, Saskia
    Koch, Martina
    Macher, Philipp
    Kimmel, Anna-Carina L.
    Steigerwald, Thomas G.
    Alt, Nicolas S. A.
    Schluecker, Eberhard
    Wellmann, Peter
    JOURNAL OF CRYSTAL GROWTH, 2017, 479 : 59 - 66