Solubility of naphthalene in liquid and supercritical ammonia

被引:0
|
作者
Kim, JR [1 ]
Lentz, H [1 ]
Park, TK [1 ]
机构
[1] UNIV GESAMTHSCH SIEGEN,FACHBEREICH 8,D-57068 SIEGEN,GERMANY
关键词
solubility; entropy; supercritical ammonia; thermodynamics;
D O I
10.1524/zpch.1996.193.Part_1_2.087
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The solubilities of naphthalene in liquid and supercritical ammonia have been measured for temperature from 333.15 to 497.15 K and pressures between 5 and 120 MPa. For pressures higher than 10 MPa and temperatures higher than 333.15 K the results can be described by a simple equation which enables interpolation and extrapolation especially with respect to pressure or density. Logarithmic isobars are not straight lines and the transition entropies calculated for temperatures higher than 373.15 K are negative at low pressures and positive for pressures higher than 22.0 MPa.
引用
收藏
页码:87 / 94
页数:8
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