Synthesis of PPP-b-PS block copolymers using a combination of Suzuki-polycondensation and nitroxide-mediated radical polymerization

被引：16
作者：
Britze, Antje [1 ]
Jacob, Josemon [2 ]
Choudhary, Veena [2 ]
Moellmann, Vera [1 ]
Grundmeier, Guido [1 ]
Luftmann, Heinrich [3 ]
Kuckling, Dirk [1 ]
机构：
[1] Univ Gesamthsch Paderborn, Dept Chem, D-33098 Paderborn, Germany
[2] IIT Delhi, Ctr Polymer Sci & Engn, New Delhi 110016, India
[3] Univ Munster, Fachbereich Chem & Pharm, D-48149 Munster, Germany
来源：
POLYMER | 2010年 / 51卷 / 23期
关键词：
Suzuki-polycondensation; Nitroxide-mediated radical polymerization; Block copolymers; pi-Conjugated segments; MORPHOLOGY; POLYMERS;
D O I：
10.1016/j.polymer.2010.09.022
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The synthesis of pi-conjugated Nitroxide-Mediated Radical Polymerization (NMRP)-macroinitiators by Suzuki-polycondensation in a one-step reaction has been investigated using conventional and microwave-heating in presence of a suitable terminating agent. Alkoxyamine-functionalized poly(para-phenylene)s were initially synthesized by Suzuki-polycondensation and then its block copolymer with styrene by NMRP. Molecular weight and molecular weight distribution of the polymers have been determined in SEC-measurements, while end-group determination was performed with MALDI-ToF-MS. Thin-layer-morphologies of the block copolymers were investigated using tapping-mode AFM. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码：5294 / 5303
页数：10
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