Synthesis of PPP-b-PS block copolymers using a combination of Suzuki-polycondensation and nitroxide-mediated radical polymerization

被引：16
作者：
Britze, Antje [1 ]
Jacob, Josemon [2 ]
Choudhary, Veena [2 ]
Moellmann, Vera [1 ]
Grundmeier, Guido [1 ]
Luftmann, Heinrich [3 ]
Kuckling, Dirk [1 ]
机构：
[1] Univ Gesamthsch Paderborn, Dept Chem, D-33098 Paderborn, Germany
[2] IIT Delhi, Ctr Polymer Sci & Engn, New Delhi 110016, India
[3] Univ Munster, Fachbereich Chem & Pharm, D-48149 Munster, Germany
来源：
POLYMER | 2010年 / 51卷 / 23期
关键词：
Suzuki-polycondensation; Nitroxide-mediated radical polymerization; Block copolymers; pi-Conjugated segments; MORPHOLOGY; POLYMERS;
D O I：
10.1016/j.polymer.2010.09.022
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The synthesis of pi-conjugated Nitroxide-Mediated Radical Polymerization (NMRP)-macroinitiators by Suzuki-polycondensation in a one-step reaction has been investigated using conventional and microwave-heating in presence of a suitable terminating agent. Alkoxyamine-functionalized poly(para-phenylene)s were initially synthesized by Suzuki-polycondensation and then its block copolymer with styrene by NMRP. Molecular weight and molecular weight distribution of the polymers have been determined in SEC-measurements, while end-group determination was performed with MALDI-ToF-MS. Thin-layer-morphologies of the block copolymers were investigated using tapping-mode AFM. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码：5294 / 5303
页数：10
相关论文
共 50 条
  • [1] Synthesis of Blockcopolymers P3HT-b-PS Using a Combination of Grignard-Metathesis and Nitroxide-Mediated Radical Polymerization
    Britze, Antje
    Moellmann, Vera
    Grundmeier, Guido
    Luftmann, Heinrich
    Kuckling, Dirk
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 2011, 212 (07) : 679 - 690
  • [2] Synthesis of Functional Syndiotactic Polystyrene Copolymers with Graft and Block Structures by Nitroxide-Mediated Living Radical Polymerization
    Abbasian, Mojtaba
    JOURNAL OF ELASTOMERS AND PLASTICS, 2011, 43 (05) : 481 - 497
  • [3] Star Block Copolymers Through Nitroxide-Mediated Radical Polymerization From Polyhedral Oligomeric Silsesquioxane (POSS) Core
    Lu, Chu-Hua
    Wang, Jui-Hsu
    Chang, Feng-Chih
    Kuo, Shiao-Wei
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 2010, 211 (12) : 1339 - 1347
  • [4] Synthesis of a bulky nitroxide and its application in the nitroxide-mediated radical polymerization
    Jing, Yuanyuan
    Tesch, Matthias
    Wang, Lin
    Daniliuc, Constantin Gabriel
    Studer, Armido
    TETRAHEDRON, 2016, 72 (48) : 7665 - 7671
  • [5] Facile and versatile synthesis of rod-coil poly(3-hexylthiophene)-based block copolymers by nitroxide-mediated radical polymerization
    Mougnier, Sebastien-Jun
    Brochon, Cyril
    Cloutet, Eric
    Magnet, Stephanie
    Navarro, Christophe
    Hadziioannou, Georges
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2012, 50 (12) : 2463 - 2470
  • [6] Preparation of main-chain imidazolium-functionalized amphiphilic block copolymers through combination of condensation polymerization and nitroxide-mediated free radical polymerization and their micelle study
    Li, Xue
    Ni, Xufeng
    Liang, Zhenhua
    Shen, Zhiquan
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2012, 50 (10) : 2037 - 2044
  • [7] Novel multi-responsive P2VP-block-PNIPAAm block copolymers via nitroxide-mediated radical polymerization
    Corten, Cathrin
    Kretschmer, Katja
    Kuckling, Dirk
    BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 2010, 6 : 756 - 765
  • [8] Synthesis of thermally responsive cylindrical molecular brushes via a combination of nitroxide-mediated radical polymerization and "grafting onto" strategy
    Gromadzki, Daniel
    Jigounov, Alexander
    Stepanek, Petr
    Makuska, Ricardas
    EUROPEAN POLYMER JOURNAL, 2010, 46 (04) : 804 - 813
  • [9] Synthesis of isoprene-based triblock copolymers by nitroxide-mediated polymerization
    Metafiot, Adrien
    Pruvost, Sebastien
    Gerard, Jean-Francois
    Defoort, Brigitte
    Maric, Milan
    EUROPEAN POLYMER JOURNAL, 2020, 134
  • [10] ABA-type liquid crystalline triblock copolymers via nitroxide-mediated radical polymerization: design, synthesis, and morphologies
    Gao, Long-Cheng
    Pan, Qi-Wei
    Wang, Chao
    Yi, Yi
    Chen, Xiao-Fang
    Fan, Xing-He
    Zhou, Qi-Feng
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2007, 45 (24) : 5949 - 5956
12345