DEEP EUTECTIC SOLVENTS;
CHOLINE CHLORIDE;
HYDROCARBONS;
SEPARATION;
EXTRACTION;
MIXTURES;
D O I:
10.1021/je100104v
中图分类号:
O414.1 [热力学];
学科分类号:
摘要:
New ionic liquids analogues, that is, deep eutectic solvents (DESs), have been successfully synthesized. These DESs have been synthesized by the reaction of phosphonium-based salts with different hydrogen bond donors. Many of these DESs have melting temperatures lower than 100 degrees C. Preliminary laboratory results showed that these DESs can be used in different applications, for example, electrochemical processes, separation of sugars, and so forth. Melting temperature, density, viscosity, pH, conductivity, and dissolved oxygen content of the novel phosphonium-based DESs were measured as a function of temperature. It was found that the type of the salt and hydrogen bond donor and the mole ratio of both compounds have a paramount effect on the studied properties.
机构:
Sultan Qaboos Univ, Petr & Chem Engn Dept, Dept Chem & Petr Engn, Muscat 123, OmanSultan Qaboos Univ, Petr & Chem Engn Dept, Dept Chem & Petr Engn, Muscat 123, Oman
Ahmed, Omar U.
Mjalli, Farouq S.
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Sultan Qaboos Univ, Petr & Chem Engn Dept, Dept Chem & Petr Engn, Muscat 123, OmanSultan Qaboos Univ, Petr & Chem Engn Dept, Dept Chem & Petr Engn, Muscat 123, Oman
Mjalli, Farouq S.
Gujarathi, Ashish M.
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Sultan Qaboos Univ, Petr & Chem Engn Dept, Dept Chem & Petr Engn, Muscat 123, OmanSultan Qaboos Univ, Petr & Chem Engn Dept, Dept Chem & Petr Engn, Muscat 123, Oman
Gujarathi, Ashish M.
Al-Wahaibi, Talal
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Sultan Qaboos Univ, Petr & Chem Engn Dept, Dept Chem & Petr Engn, Muscat 123, OmanSultan Qaboos Univ, Petr & Chem Engn Dept, Dept Chem & Petr Engn, Muscat 123, Oman
Al-Wahaibi, Talal
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机构:
Al-Wahaibi, Yahya
AI-Nashef, Inas M.
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机构:
Masdar Inst Sci & Technol, Dept Chem & Environm Engn, Abu Dhabi, U Arab EmiratesSultan Qaboos Univ, Petr & Chem Engn Dept, Dept Chem & Petr Engn, Muscat 123, Oman
机构:
Yangtze Normal Univ, Key Lab Extraordinary Bond Engn & Adv Mat Technol, Chongqing, Peoples R China
Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou, Gansu, Peoples R ChinaYangtze Normal Univ, Key Lab Extraordinary Bond Engn & Adv Mat Technol, Chongqing, Peoples R China
Zhu, Lili
Dong, Jun
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Yangtze Normal Univ, Key Lab Extraordinary Bond Engn & Adv Mat Technol, Chongqing, Peoples R ChinaYangtze Normal Univ, Key Lab Extraordinary Bond Engn & Adv Mat Technol, Chongqing, Peoples R China
Dong, Jun
Ma, Ying
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Yangtze Normal Univ, Key Lab Extraordinary Bond Engn & Adv Mat Technol, Chongqing, Peoples R ChinaYangtze Normal Univ, Key Lab Extraordinary Bond Engn & Adv Mat Technol, Chongqing, Peoples R China
Ma, Ying
Jia, Yulong
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Yangtze Normal Univ, Key Lab Extraordinary Bond Engn & Adv Mat Technol, Chongqing, Peoples R ChinaYangtze Normal Univ, Key Lab Extraordinary Bond Engn & Adv Mat Technol, Chongqing, Peoples R China
Jia, Yulong
Peng, Cheng
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Yangtze Normal Univ, Key Lab Extraordinary Bond Engn & Adv Mat Technol, Chongqing, Peoples R ChinaYangtze Normal Univ, Key Lab Extraordinary Bond Engn & Adv Mat Technol, Chongqing, Peoples R China
Peng, Cheng
Li, Weimin
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Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou, Gansu, Peoples R ChinaYangtze Normal Univ, Key Lab Extraordinary Bond Engn & Adv Mat Technol, Chongqing, Peoples R China
Li, Weimin
Zhang, Ming
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Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou, Gansu, Peoples R ChinaYangtze Normal Univ, Key Lab Extraordinary Bond Engn & Adv Mat Technol, Chongqing, Peoples R China
Zhang, Ming
Gong, Kuiliang
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Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou, Gansu, Peoples R China
Chinese Acad Sci, Lanzhou Inst Chem Phys, Qingdao Ctr Resource Chem & New Mat, Qingdao, Shandong, Peoples R ChinaYangtze Normal Univ, Key Lab Extraordinary Bond Engn & Adv Mat Technol, Chongqing, Peoples R China
Gong, Kuiliang
Wang, Xiaobo
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Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou, Gansu, Peoples R ChinaYangtze Normal Univ, Key Lab Extraordinary Bond Engn & Adv Mat Technol, Chongqing, Peoples R China