Polyoxotungstate Incorporating Organotriphosphonate Ligands: Synthesis, Characterization, and Catalytic for Alkene Epoxidation

被引：40
作者：
Huo, Yu [1 ]
Huo, Zhiyuan [1 ]
Ma, Pengtao [1 ]
Wang, Jingping [1 ]
Niu, Jingyang [1 ]
机构：
[1] Henan Univ, Coll Chem & Chem Engn, Key Lab Polyoxometalate Chem Henan Prov, Kaifeng 475004, Peoples R China
来源：
INORGANIC CHEMISTRY | 2015年 / 54卷 / 02期
基金：
中国国家自然科学基金;
关键词：
POLYOXOMETALATE; CHEMISTRY; VALENCE; CLUSTER; H2O2;
D O I：
10.1021/ic502404m
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A S-shaped organotriphosphonate polyoxotungstate, K4H6[H-4{(AsW9O33)Zn(H2O)W5O11(N(CH2PO3)(3))}(2)(mu(2)-O)(2)].27H(2)O (1), has been synthesized and characterized. Compound 1 contains a different geometry of [{Zn(H2O)W5O19(N(CH2PO3)(3))}](12-) clusters, which forms a chiral conformation. The catalysis of 1 for alkene epoxidation was investigated with a hydrogen peroxide (H2O2) oxidant.
引用
收藏
页码：406 / 408
页数：3
相关论文
共 40 条
[1]   Diphosphates and diphosphonates in polyoxometalate chemistry [J].
Banerjee, Abhishek ;
Bassil, Bassem S. ;
Roeschenthaler, Gerd-Volker ;
Kortz, Ulrich .
CHEMICAL SOCIETY REVIEWS, 2012, 41 (22) :7590-7604
[2]   Cobalt, Manganese, Nickel, and Vanadium Derivatives of the Cyclic 48-Tungsto-8-Phosphate [H7P8W48O184]33- [J].
Bassil, Bassem S. ;
Ibrahim, Masooma ;
Mal, Sib Sankar ;
Suchopar, Andreas ;
Biboum, Rosa Ngo ;
Keita, Bineta ;
Nadjo, Louis ;
Nellutla, Saritha ;
van Tol, Johan ;
Dalal, Naresh S. ;
Kortz, Ulrich .
INORGANIC CHEMISTRY, 2010, 49 (11) :4949-4959
[3]   Fast catalytic epoxidation with H2O2 and [γ-SiW10O36(PhPO)2]4 in ionic liquids under microwave irradiation [J].
Berardi, Serena ;
Bonchio, Marcella ;
Carraro, Mauro ;
Conte, Valeria ;
Sartorel, Andrea ;
Scorrano, Gianfranco .
JOURNAL OF ORGANIC CHEMISTRY, 2007, 72 (23) :8954-8957
[4]   Hybrid Polyoxometalates: Merging Organic and Inorganic Domains for Enhanced Catalysis and Energy Applications [J].
Berardi, Serena ;
Carraro, Mauro ;
Sartorel, Andrea ;
Modugno, Gloria ;
Bonchio, Marcella .
ISRAEL JOURNAL OF CHEMISTRY, 2011, 51 (02) :259-274
[5]   Photooxidation in water by new hybrid molecular photocatalysts integrating an organic sensitizer with a polyoxometalate core [J].
Bonchio, M ;
Carraro, M ;
Scorrano, G ;
Bagno, A .
ADVANCED SYNTHESIS & CATALYSIS, 2004, 346 (06) :648-654
[6]   BOND-VALENCE PARAMETERS OBTAINED FROM A SYSTEMATIC ANALYSIS OF THE INORGANIC CRYSTAL-STRUCTURE DATABASE [J].
BROWN, ID ;
ALTERMATT, D .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1985, 41 (AUG) :244-247
[7]  
Burgomaster P. D., 2010, CRYST GROWTH DES, V10, P2209
[8]   Hybrid polyoxotungstates as second-generation POM-based catalysts for microwave-assisted H2O2 activation [J].
Carraro, Mauro ;
Sandei, Luca ;
Sartorel, Andrea ;
Scorrano, Gianfranco ;
Bonchio, Marcella .
ORGANIC LETTERS, 2006, 8 (17) :3671-3674
[9]   Functionalized polyoxometalates with covalently linked bisphosphonate, N-donor or carboxylate ligands: from electrocatalytic to optical properties [J].
Dolbecq, Anne ;
Mialane, Pierre ;
Secheresse, Francis ;
Keita, Bineta ;
Nadjo, Louis .
CHEMICAL COMMUNICATIONS, 2012, 48 (67) :8299-8316
[10]   Synthesis and spectroscopic characterization of organophosphono derivatives of lindqvist niobotungstates -: X-ray crystal structures of (nBu4N)3[NbW10O38(RP)2] (R = nBu, Hep and Ph) [J].
Driss, Hafedh ;
Boubekeur, Kamal ;
Debbabi, Mongi ;
Thouvenot, Rene .
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2008, (23) :3678-3686
1234