Cation-dependent non linear optical behavior in an octupolar 3D anionic metal-organic open framework

被引：148
|
作者：
Liu, Yan
Li, Gao
Li, Xing
Cui, Yong
机构：
[1] Shanghai Jiao Tong Univ, Sch Chem & Chem Technol, Shanghai 200240, Peoples R China
[2] Ningbo Univ, Sch Mat Sci & Chem Engn, Zhejiang 315211, Peoples R China
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 33期
关键词：
ion exchange; materials science; nonlinear optics; organic-inorganic hybrid composites; porosity;
D O I：
10.1002/anie.200701056
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Figure Presented) A holey host: An octupolar porous metal-organic framework with a Td-symmetric supercage structure (see picture; green: center of the octapolar structure) exhibits a powder second harmonic generation (SHG) intensity about 15 times higher than that of KH 2PO4. This anionic open framework is highly thermally stable, displays high ion-exchange capacities with the cations NH 4+, Na+, and K+, and, more importantly, exhibits an unprecedented cation-dependent NLO activity. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：6301 / 6304
页数：4
相关论文
共 50 条
  • [31] Dimension-dependent fluorescence emission and photoelectric performances of a 3D pyrene-based metal-organic framework
    Xiao, Zhi
    Li, Dong-Bin
    Zhang, Li-Guo
    Wang, Hua-Rui
    Qin, Jian-Hua
    Yang, Xiao-Gang
    Wu, Ya-Pan
    Ma, Lu-Fang
    Li, Dong-Sheng
    JOURNAL OF SOLID STATE CHEMISTRY, 2023, 317
  • [32] A 3D porous metal-organic framework containing nanotubes based on multiple helices
    Hou, Lei
    Jia, Li-Na
    Shi, Wen-Juan
    Du, Li-Yun
    Li, Jiang
    Wang, Yao-Yu
    Shi, Qi-Zhen
    DALTON TRANSACTIONS, 2013, 42 (18) : 6306 - 6309
  • [33] 3D porous metal-organic framework as an efficient electrocatalyst for nonenzymatic sensing application
    Zhang, Daojun
    Zhang, Jingchao
    Zhang, Renchun
    Shi, Huaizhong
    Guo, Yuanyuan
    Guo, Xiuli
    Li, Sujuan
    Yuan, Bailling
    TALANTA, 2015, 144 : 1176 - 1181
  • [34] A luminescent 3D interpenetrating metal-organic framework for highly selective sensing of nitrobenzene
    Singh, Divyendu
    Nagaraja, C. M.
    DALTON TRANSACTIONS, 2014, 43 (48) : 17912 - 17915
  • [35] Two-Photon 3D Printing in Metal-Organic Framework Single Crystals
    Zhang, Yusheng
    Su, Yuming
    Zhao, Yi
    Wang, Zhiye
    Wang, Cheng
    SMALL, 2022, 18 (18)
  • [36] A Multifunctional 3D Ferroelectric and NLO-Active Porous Metal-Organic Framework
    Guo, Zhengang
    Cao, Rong
    Wang, Xin
    Li, Hongfang
    Yuan, Wenbing
    Wang, Guojian
    Wu, Haohan
    Li, Jing
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (20) : 6894 - +
  • [37] Anisotropic thermal expansion of a 3D metal-organic framework with hydrophilic and hydrophobic pores
    Kondo, Atsushi
    Maeda, Kazuyuki
    JOURNAL OF SOLID STATE CHEMISTRY, 2015, 221 : 126 - 131
  • [38] Decoupled Solar Energy Storage and Dark Photocatalysis in a 3D Metal-Organic Framework
    Stanley, Philip M.
    Sixt, Florian
    Warnan, Julien
    ADVANCED MATERIALS, 2023, 35 (01)
  • [39] Metal-organic framework mixed-matrix coatings on 3D printed devices
    Figuerola, Andreu
    Medina, Deyber A. V.
    Santos-Neto, Alvaro J.
    Cabello, Carlos Palomino
    Cerda, Victor
    Palomino, Gemma Turnes
    Maya, Fernando
    APPLIED MATERIALS TODAY, 2019, 16 : 21 - 27
  • [40] Photocatalytic decontamination of methyl violet by a 3D twofold interpenetrating metal-organic framework
    Zhou, En-Hong
    Hu, Wuxin
    Ding, Qiongjie
    Li, Letong
    Liao, Zehao
    Jin, Jun-Cheng
    INORGANIC CHEMISTRY COMMUNICATIONS, 2020, 120
12345