Cation-dependent non linear optical behavior in an octupolar 3D anionic metal-organic open framework

被引：148
|
作者：
Liu, Yan
Li, Gao
Li, Xing
Cui, Yong
机构：
[1] Shanghai Jiao Tong Univ, Sch Chem & Chem Technol, Shanghai 200240, Peoples R China
[2] Ningbo Univ, Sch Mat Sci & Chem Engn, Zhejiang 315211, Peoples R China
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 33期
关键词：
ion exchange; materials science; nonlinear optics; organic-inorganic hybrid composites; porosity;
D O I：
10.1002/anie.200701056
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Figure Presented) A holey host: An octupolar porous metal-organic framework with a Td-symmetric supercage structure (see picture; green: center of the octapolar structure) exhibits a powder second harmonic generation (SHG) intensity about 15 times higher than that of KH 2PO4. This anionic open framework is highly thermally stable, displays high ion-exchange capacities with the cations NH 4+, Na+, and K+, and, more importantly, exhibits an unprecedented cation-dependent NLO activity. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：6301 / 6304
页数：4
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