Design and Synthesis of a Class of Aromatic Polyamide Foldamer

被引：3
|
作者：
Wang, Heng [1 ,2 ]
Zhang, Yukun [1 ,2 ]
Zou, Sheng [1 ]
Cao, Jinxin [1 ]
Huang, Qingfei [1 ]
Wang, Qiwei [1 ]
Zhu, Jin [1 ]
机构：
[1] Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Sichuan, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
来源：
CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2018年 / 38卷 / 08期
基金：
中国国家自然科学基金;
关键词：
aromatic polyamide; foldamer; helice; OLIGOMERS; MACROCYCLES; PEPTIDES; FAMILY; HELIX;
D O I：
10.6023/cjoc201712043
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Long aromatic polymer chains which based on 3,5-diaminobenzoic acid derivatives and 4,6-dihydroxyisophthalic acid derivatives are designed and synthesized. The results of solubility, NMR, UV-Vis spectrum and circular dichroism (CD) experiments indicate that the polymer adopts a hollow helical conformation that is stablized by intramolecular H-bonding interaction between side chains.
引用
收藏
页码：2060 / 2066
页数：7
相关论文
共 35 条
  • [1] Aimin Z., 2006, ORG LETT, V8, P5117
  • [2] beta-peptide foldamers: Robust Helix formation in a new family of beta-amino acid oligomers
    Appella, DH
    Christianson, LA
    Karle, IL
    Powell, DR
    Gellman, SH
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (51) : 13071 - 13072
  • [3] Preparation and helical folding of aromatic polyamides
    Cao, Jinxin
    Kline, Mark
    Chen, Zhongzhu
    Luan, Bao
    Lv, Menglan
    Zhang, Wenrui
    Lian, Chunxia
    Wang, Qiwei
    Huang, Qingfei
    Wei, Xiaoxi
    Deng, Jingen
    Zhu, Jin
    Gong, Bing
    [J]. CHEMICAL COMMUNICATIONS, 2012, 48 (90) : 11112 - 11114
  • [4] Creighton T., 1993, Proteins Structures and Molecular Properties
  • [5] Efficient Kinetic Macrocyclization
    Feng, Wen
    Yamato, Kazuhiro
    Yang, Liuqing
    Ferguson, Joseph S.
    Zhong, Lijian
    Zou, Shuliang
    Yuan, Lihua
    Zeng, Xiao Cheng
    Gong, Bing
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (07) : 2629 - 2637
  • [6] High-performance aromatic polyamides
    Garcia, Jose M.
    Garcia, Felix C.
    Serna, Felipe
    de la Pena, Jose L.
    [J]. PROGRESS IN POLYMER SCIENCE, 2010, 35 (05) : 623 - 686
  • [7] Foldamers: A manifesto
    Gellman, SH
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 1998, 31 (04) : 173 - 180
  • [8] Gong B, 2001, CHEM-EUR J, V7, P4336, DOI 10.1002/1521-3765(20011015)7:20<4336::AID-CHEM4336>3.0.CO
  • [9] 2-1
  • [10] Hollow Crescents, Helices, and Macrocycles from Enforced Folding and Folding-Assisted Macrocyclization
    Gong, Bing
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2008, 41 (10) : 1376 - 1386
1234