Anion exchange capacity is a key factor for the application of Zn-Al layered double hydroxides (LDHs) as nano-containers in active corrosion protection. In this work, the nitrate-pyrovanadate anion exchange/re-exchange processes in these LDHs were investigated in situ. We demonstrate that the exchange reactions lead to a decrease of the average crystallite size of LDHs as a result of mechanical fragmentation of the crystallites rather than dissolution/recrystallization. The fragmentation occurs due to fast anion exchange in the initial stage, and can be controlled by changing the ratio of the available substituent anions to the replacement anions and application of a mechanical activation. (C) 2010 Elsevier B.V. All rights reserved.
机构:
Univ Clermont Ferrand, CNRS UMR 6002, Lab Mat Inorgan, F-63177 Aubiere, FranceUniv Clermont Ferrand, CNRS UMR 6002, Lab Mat Inorgan, F-63177 Aubiere, France
Leroux, F
Besse, JP
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Univ Clermont Ferrand, CNRS UMR 6002, Lab Mat Inorgan, F-63177 Aubiere, FranceUniv Clermont Ferrand, CNRS UMR 6002, Lab Mat Inorgan, F-63177 Aubiere, France
机构:
Univ Clermont Ferrand, CNRS UMR 6002, Lab Mat Inorgan, F-63177 Aubiere, FranceUniv Clermont Ferrand, CNRS UMR 6002, Lab Mat Inorgan, F-63177 Aubiere, France
Leroux, F
Besse, JP
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h-index: 0
机构:
Univ Clermont Ferrand, CNRS UMR 6002, Lab Mat Inorgan, F-63177 Aubiere, FranceUniv Clermont Ferrand, CNRS UMR 6002, Lab Mat Inorgan, F-63177 Aubiere, France