Magnetically Recoverable Catalysts: Beyond Magnetic Separation

被引:41
作者
Shifrina, Zinaida B. [1 ]
Bronstein, Lyudmila M. [1 ,2 ,3 ]
机构
[1] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Moscow, Russia
[2] Indiana Univ, Dept Chem, Bloomington, IN USA
[3] King Abdulaziz Univ, Fac Sci, Dept Phys, Jeddah, Saudi Arabia
基金
俄罗斯科学基金会;
关键词
magnetically recoverable catalysts; iron oxide influence; catalytic species distribution; graphene derivative; side reactions; IRON-OXIDE NANOPARTICLES; METHANOL SYNTHESIS; BIO-OIL; CELLULOSE CONVERSION; REACTION-MECHANISM; HYDROGENATION; NANOCATALYSTS; HYDROCARBONS; GRAPHENE; ALCOHOLS;
D O I
10.3389/fchem.2018.00298
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Here, we discuss several important aspects of magnetically recoverable catalysts which can be realized when magnetic oxide nanoparticles are exposed to catalytic species and catalytic reaction media. In such conditions magnetic oxides can enhance performance of catalytic nanoparticles due to (i) electronic effects, (ii) catalyzing reactions which are beneficial for the final reaction outcome, or (iii) providing a capacity to dilute catalytic metal oxide species, leading to an increase of oxygen vacancies. However, this approach should be used when the magnetic oxides are stable in reaction conditions and do not promote side reactions. Incorporation of another active component, i.e., a graphene derivative, in the magnetically recoverable catalyst constitutes a smart design of a catalytic system due to synergy of its components, further enhancing catalytic properties.
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页数:6
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