Fluoride displacement by lithium reagents.: An improved method for the synthesis of nickel hydroxo, alkoxo, and amido complexes

被引：43
作者：
Cámpora, J
Matas, I
Palma, P
Graiff, C
Tiripicchio, A
机构：
[1] Univ Sevilla, Inst Invest Quim, CSIC, Seville 41092, Spain
[2] Univ Parma, Dipartimento Chim Gen & Inorgan Chim Analit Chim, I-43100 Parma, Italy
来源：
ORGANOMETALLICS | 2005年 / 24卷 / 12期
关键词：
D O I：
10.1021/om0489709
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The complex Ni(Me)(F)(dippe) undergoes clean fluoride displacement reactions with Li(OH), Li((OBu)-Bu-t), and Li(NC4H8), affording the corresponding cis hydroxo, alkoxo, and amido methyl derivatives. These compounds display limited thermal stability and decompose by beta-hydrogen elimination or disproportionation processes under mild conditions.
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页码：2827 / 2830
页数：4
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