COMPOUNDS FEATURING THE STRUCTURAL FRAGMENT P-C-P

被引：1

作者：

Shevchenko, I. ^{[1
]}

Tarasevich, A. ^{[1
]}

Turcheniuk, K. ^{[1
]}

Mikolenko, R. ^{[1
]}

Andrushko, V. ^{[1
]}

Rozhenko, A. ^{[2
]}

Schmutzler, R. ^{[3
]}

Gruetzmacher, H. ^{[4
]}

Roeschenthaler, G. -V. ^{[5
]}

机构：

[1] Natl Acad Sci Ukraine, Inst Bioorgan Chem & Petrochem, UA-02094 Kiev, Ukraine

[2] Natl Acad Sci Ukraine, Inst Organ Chem, UA-02094 Kiev, Ukraine

[3] Tech Univ, Inst Inorgan & Analyt Chem, Braunschweig, Germany

[4] ETH Zentrum, Inorgan Chem Lab, Zurich, Switzerland

[5] Jacobs Univ Gmbh, Bremen, Germany

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2011年 / 186卷 / 04期

基金：

瑞士国家科学基金会;

关键词：

Azaphospholes; diphosphiranes; hypervalency; phosphanes; ylides; zwitterions; HEXAFLUOROACETONE; OXIDATION;

D O I：

10.1080/10426507.2010.520285

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This article summarizes some of our investigations of compounds featuring the structural fragment P-C-P. Phosphorus atoms in different oxidation states and coordination numbers display different chemical behaviors. This may lead to unique chemical properties when they are bridged by a methylene group in a P-CH2-P system. For example, the P-III-CH2-P(V)unit is able to add different unsaturated compounds to give zwitterionic products with oppositely charged phosphorus atoms. In addition, the two hydrogen atoms in P-CH2-P may also take part in different transformations, resulting in the formation of carbodiphosphoranes or in the formation of a direct P-P bond to give three-membered ring diphosphiranes.

引用

页码：621 / 625

页数：5

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