Synthesis of heteroleptic Cerium(IV) complexes using a heptadentate (N4O3) tripodale Schiff-base ligand

被引：33

作者：

Droese, Peter ^{[1
]}

Gottfriedsen, Jochen ^{[1
]}

机构：

[1] Univ Magdeburg, Inst Chem, D-39106 Magdeburg, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2008年 / 634卷 / 01期

关键词：

Cerium; Schiff-base ligands;

D O I：

10.1002/zaac.200700312

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The Cerium(IV) complexes [{N[CH2CH2N=CH(2-O-3,5-'Bu2C6H2)(3)}CeCl] (1) and [{N[CH2CH2N=CH(2-O-3,5'Bu2C6H2)](3)}Ce(NO3)] (2) were derived from the condensation of tris(2-aminoethyl)amine and 3,5-di-tert-butylsalicylaldehyde and the appropriate Ce starting material CeCl3(H2O)(6) and (NH4)(2)[Ce(NO3)(6)], respectively. Single crystal X-ray diffraction studies reveal monomeric complexes.

引用

页码：87 / 90

页数：4

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