Ion-pairing assemblies of heteroporphyrin-based π-electronic cation with various counteranions

被引:3
|
作者
Fujita, Masaki [1 ]
Haketa, Yohei [1 ]
Tanaka, Hiroki [1 ]
Yasuda, Nobuhiro [2 ]
Maeda, Hiromitsu [1 ]
机构
[1] Ritsumeikan Univ, Coll Life Sci, Dept Appl Chem, Kusatsu 5258577, Japan
[2] Japan Synchrotron Radiat Res Inst, Diffract & Scattering Div, Sayo 6795198, Japan
关键词
COMPLEXES; DIPYRROLYLDIKETONE;
D O I
10.1039/d2cc02345h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Various counteranions of the thiaporphyrin-Ni-II complex as a pi-electronic cation were exchanged for preparing stable ion pairs. The ion-pairing assembling modes, which included contributions of charge-by-charge and charge-segregated modes, and properties depended on the geometries and electronic states of the counteranions.
引用
收藏
页码:9870 / 9873
页数:5
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