The first example of a hetero-tetranuclear [(VO)Gd]2 complex:: synthesis, crystal structure and magnetic properties of [VOLGd(hfa)2CH3OH]2•2CH3OH•2(CH3)2CO

被引：17
作者：
Costes, JP
Shova, S
Clemente Juan, JM
Suet, N
机构：
[1] CNRS, Chim Coordinat Lab, F-31077 Toulouse, France
[2] Moldova State Univ, Dept Chem, Kishinev 2009, Moldova
[3] Univ Valencia, Inst Ciencia Mol, E-46100 Burjassot, Spain
来源：
DALTON TRANSACTIONS | 2005年 / 17期
关键词：
D O I：
10.1039/b506102d
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A cyclic tetranuclear [(VO)-O-IV-Gd-III](2) complex with VO and Gd ions alternately arrayed, behaves, from the magnetic point of view, as two independent dinuclear entities each having a S = 4 ground state, as a consequence of an active and ferromagnetic VO-Gd interaction through the double phenoxo bridge and a magnetically inactive VO-Gd interaction through the amide bridge.
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页码：2830 / 2832
页数：3
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