Absorption and emission spectral studies of Sm3+-doped lead tungstate tellurite glasses

被引:78
作者
Babu, A. Mohan [1 ]
Jamalaiah, B. C. [1 ,3 ]
Sasikala, T. [1 ]
Saleem, S. A. [2 ]
Moorthy, L. Rama [1 ]
机构
[1] Sri Venkateswara Univ, Dept Phys, Tirupati 517502, Andhra Pradesh, India
[2] Govt Degree Coll, Dept Phys, Nagari 517590, India
[3] Pukyong Natl Univ, Dept Phys, Pusan 608737, South Korea
关键词
Amorphous materials; Optical properties; Luminescence; Optical spectroscopy; OPTICAL-PROPERTIES; SM3+ IONS; PHOTOLUMINESCENCE PROPERTIES; LITHIUM BORATE; OXIDE; FLUORESCENCE; TRANSITIONS; INTENSITIES; LASER; ER3+;
D O I
10.1016/j.jallcom.2011.01.136
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The present work reports the effect of concentration on photoluminescence properties of Sm3+ ions doped lead tungstate tellurite (LTTSm) glasses by using the absorption, emission and decay measurements. The Judd-Ofelt theory has been used to evaluate the three Judd-Ofelt intensity parameters (ohm(2,4,6)) and calculated oscillator strengths (f(c)). LTTSm glasses exhibited intense reddish-orange emission when excited with 477nm wavelength. Concentration quenching has been noticed beyond 1.0 mol% of Sm3+ ion concentration. The decay curves of (4)G(5/2) level exhibited single exponential behavior for all the concentrations and the measured lifetimes are found to depend strongly on Sm3+ concentration. From the emission characteristic parameters of (4)G(5/2) level, it is concluded that the LTTSm glasses could be useful for photonic devices like visible lasers, fluorescent display devices and optical amplifiers. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:4743 / 4747
页数:5
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