Theoretical search for spintronic and electrochromic device materials based on Li-intercalated transition-metal-doped anatase TiO2 -: art. no. 033202

被引：15

作者：

Park, MS ^{[1
]}

Min, BI

机构：

[1] Pohang Univ Sci & Technol, Dept Phys, Pohang 790784, South Korea

[2] Pohang Univ Sci & Technol, Electron Spin Sci Ctr, Pohang 790784, South Korea

来源：

PHYSICAL REVIEW B | 2003年 / 68卷 / 03期

关键词：

D O I：

10.1103/PhysRevB.68.033202

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

We have explored the effects of Li intercalation on the electronic and magnetic properties of transition-metal (TM) doped anatase TiO2. By Li intercalation, Mn-doped TiO2 exhibits a insulator to metal transition. On the other hand, Li-intercalated Fe-doped TiO2 has an insulating ground state for a low concentration of Li/Ti =0.067, but a metallic ground state for a high concentration of Li/Ti=0.133. We discuss the n-type carrier induced ferromagnetism in Li-intercalated TM-doped anatase TiO2. Based on the Li-intercalated TM-doped anatase TiO2, we propose a potential spintronic and electrochromic device controlled by an electric field.

引用

页数：4

共 23 条

[21] Epitaxial growth and characteristics of N-doped anatase TiO2 films grown using a free-radical nitrogen oxide source -: art. no. 123511
Matsui, H
Tabata, H
Hasuike, N
Harima, H
Mizobuchi, B
JOURNAL OF APPLIED PHYSICS, 2005, 97 (12)
[22] Catalytic role of metal oxides in gold-based catalysts:: A first principles study of CO oxidation on TiO2 supported Au -: art. no. 266102
Liu, ZP
Gong, XQ
Kohanoff, J
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PHYSICAL REVIEW LETTERS, 2003, 91 (26)
[23] Photoemission study of the metal-insulator transition in VO2/TiO2(001):: Evidence for strong electron-electron and electron-phonon interaction -: art. no. 165104
Okazaki, K
Wadati, H
Fujimori, A
Onoda, M
Muraoka, Y
Hiroi, Z
PHYSICAL REVIEW B, 2004, 69 (16) : 165104 - 1

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