Effect of alloying elements on carbon solubility in liquid silicon equilibrated with silicon carbide

被引:10
|
作者
Yanaba, K [1 ]
Matsumura, Y [1 ]
Narushima, T [1 ]
Iguchi, Y [1 ]
机构
[1] Tohoku Univ, Grad Sch Engn, Dept Met, Sendai, Miyagi 9808579, Japan
来源
MATERIALS TRANSACTIONS JIM | 1998年 / 39卷 / 08期
关键词
silicon; carbon; solubility; silicon carbide; thermodynamics; equilibrium; alloying element; interaction parameter;
D O I
10.2320/matertrans1989.39.819
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Carbon solubilities in liquid Si-X alloys (where X represents the alloying elements) that have been equilibrated with silicon carbide were determined in the temperature range between 1723 and 1873 K. The Si-X alloy was melted in a silicon carbide crucible under Ar-CO mixture gas flowing. After the equilibrium between the liquid silicon and silicon carbide was established, the carbon content and alloying element (X) content of the quenched sample were measured. The carbon solubility increased as B, Al, P and Ca contents increased in the liquid silicon, but decreased as Ti, V, Cr, Mn, Fe, Co, Ni and Cu contents increased. The effect of the alloying elements on the carbon solubility was discussed thermodynamically.
引用
收藏
页码:819 / 823
页数:5
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