A comparative study on properties of synthesized MgO with different templates

被引:42
作者
Gh, A. Bagheri [1 ]
Sabbaghan, M. [2 ]
Mirgani, Z. [1 ]
机构
[1] Islamic Azad Univ, Ctr Tehran Branch, Dept Chem, Tehran, Iran
[2] Shahid Rajaiee Teacher Training Univ, Fac Sci, Dept Chem, Tehran, Iran
关键词
MgO; Template; SEM; XRD; Degradation; Indigo carmine; COMBUSTION SYNTHESIS; GROWTH-MECHANISM; TEXTILE DYES; DECOMPOSITION; NANOPARTICLES; MG(OH)(2); REMOVAL; ZNO;
D O I
10.1016/j.saa.2014.08.059
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
Magnesium oxide powders have been prepared by simple method using different templates as Hexamine (T1), alkylate-hexamine salt (T2) and alkylate-dihexamine salt (T3). The annealed products were systematically investigated by using X-ray diffraction (XRD), energy dispersive X-ray spectroscopy (EDX), scanning electron microscopy (SEM) and UV-Visible absorption. It was found that the formation of nanoparticle could involved the role of performed "nucleus" and used template to control the growth rate of nucleuses. The results were shown that different templates affect on the size and species of particles. In this study, the crystallite size of the MgO products were in a range from 4 to 7 nm. The optical band gap of MgO nanoparticles was in the range 4.27-4.77 eV. The morphology of MgO was nanospheres or nanokong-elemere-like. In this investigation photocatalytic degradation of Indigo carmine (IC) in water was studied. The effects of some parameters such as pH, amount of catalyst, initial concentration of dye were examined. (C) 2014 Published by Elsevier B.V.
引用
收藏
页码:1286 / 1291
页数:6
相关论文
共 31 条
[1]   Combustion synthesis and nanomaterials [J].
Aruna, Singanahally T. ;
Mukasyan, Alexander S. .
CURRENT OPINION IN SOLID STATE & MATERIALS SCIENCE, 2008, 12 (3-4) :44-50
[2]   Synthesis of carbon-coated MgO nanoparticles [J].
Bedilo, AF ;
Sigel, MJ ;
Koper, OB ;
Melgunov, MS ;
Klabunde, KJ .
JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (12) :3599-3604
[3]   Evaluation of the toxicity and teratogenity of six commercial textile dyes using the frog embryo teratogenesis assay-Xenopus [J].
Birhanli, A ;
Ozmen, M .
DRUG AND CHEMICAL TOXICOLOGY, 2005, 28 (01) :51-65
[4]   Quasi-one dimensional metal oxide semiconductors: Preparation, characterization and application as chemical sensors [J].
Comini, E. ;
Baratto, C. ;
Faglia, G. ;
Ferroni, M. ;
Vomiero, A. ;
Sberveglieri, G. .
PROGRESS IN MATERIALS SCIENCE, 2009, 54 (01) :1-67
[5]  
Cullity BD, 2001, Elements of X-ray Diffraction
[6]   Kinetic modeling of photocatalytic degradation of Acid Red 27 in UV/TiO2 process [J].
Daneshvar, N ;
Rabbani, M ;
Modirshahla, N ;
Behnajady, MA .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2004, 168 (1-2) :39-45
[7]   Electrochemical oxidation of textile dye indigo [J].
Dogan, D ;
Türkdemir, H .
JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY, 2005, 80 (08) :916-923
[8]   Removal of synthetic dyes from wastewaters:: a review [J].
Forgacs, E ;
Cserháti, T ;
Oros, G .
ENVIRONMENT INTERNATIONAL, 2004, 30 (07) :953-971
[9]   Cobalt sorption properties of MgO prepared by solution combustion [J].
Granados-Correa, F. ;
Bonifacio-Martinez, J. ;
Lara, V. H. ;
Bosch, P. ;
Bulbulian, S. .
APPLIED SURFACE SCIENCE, 2008, 254 (15) :4688-4694
[10]   Decolorization of mixtures of different reactive textile dyes by the white-rot basidiomycete Phanerochaete sordida and inhibitory effect of polyvinyl alcohol [J].
Harazono, K ;
Nakamura, K .
CHEMOSPHERE, 2005, 59 (01) :63-68